Dielectric properties of (FeCoCrMnZn)3O4 high-entropy oxide at high pressure
Zheng, Zhi1,3; Liang, Bingliang2; Gao, Jing3; Ren, Jianyi2; Liu, Zhiyong2; Hou, Xue3; Sun, Jianhui1,3; Mei, Shenghua1,3
刊名CERAMICS INTERNATIONAL
2023-10-15
卷号49期号:20页码:32521-32527
关键词High-entropy oxide High pressure Dielectric properties Diamond anvil cell
ISSN号0272-8842
DOI10.1016/j.ceramint.2023.07.215
通讯作者Mei, Shenghua
英文摘要

The emerging high-entropy oxides (HEOs) have been considered promising candidates in numerous applications due to their unique properties. Yet the dielectric properties of HEOs at high pressure remain to be disclosed. In this work, the dielectric properties of (FeCoCrMnZn)(3)O-4 at high pressures up to similar to 20 GPa were systematically investigated. Combined with in-situ Raman, XRD, and impedance measurements, it is revealed that high-pressure exhibits a significant impact on the dielectric properties, even without the observed phase transition. The electric resistance, which is dominantly contributed by grain resistance, decreases exponentially with the increase of pressure. On the other hand, the relative permittivity decreases linearly with increasing pressure. In addition, the dielectric relaxation behavior of (FeCoCrMnZn)(3)O-4 at high pressure is revealed. Our results provide the experimental basis for the high-pressure effect on the dielectric properties of (FeCoCrMnZn)(3)O-4 and potential guidance for the design strategy of HEOs under extreme conditions.

资助项目Open Project Program of Yazhou Bay Innovation Institute of Hainan Tropical Ocean University[2022CXYKFTK14] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22040501] ; Department of Science and Technology of Hainan Province[ZY2021HN15] ; National Natural Science Foundation of China[52162019] ; National Natural Science Foundation of China[51664043] ; Synergetic Extreme Condition User Facility (SECUF)
WOS关键词CERAMICS
WOS研究方向Materials Science
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:001076918500001
资助机构Open Project Program of Yazhou Bay Innovation Institute of Hainan Tropical Ocean University ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Department of Science and Technology of Hainan Province ; National Natural Science Foundation of China ; Synergetic Extreme Condition User Facility (SECUF)
内容类型期刊论文
源URL[http://ir.idsse.ac.cn/handle/183446/10525]  
专题深海科学研究部_地外海洋系统研究室
通讯作者Mei, Shenghua
作者单位1.Hainan Deep Sea Technol Innovat Ctr, Sanya 572000, Peoples R China
2.Nanchang Hangkong Univ, Sch Mat Sci & Engn, Nanchang 330063, Peoples R China
3.Chinese Acad Sci, Inst Deep Sea Sci & Engn, Sanya 572000, Peoples R China
推荐引用方式
GB/T 7714
Zheng, Zhi,Liang, Bingliang,Gao, Jing,et al. Dielectric properties of (FeCoCrMnZn)3O4 high-entropy oxide at high pressure[J]. CERAMICS INTERNATIONAL,2023,49(20):32521-32527.
APA Zheng, Zhi.,Liang, Bingliang.,Gao, Jing.,Ren, Jianyi.,Liu, Zhiyong.,...&Mei, Shenghua.(2023).Dielectric properties of (FeCoCrMnZn)3O4 high-entropy oxide at high pressure.CERAMICS INTERNATIONAL,49(20),32521-32527.
MLA Zheng, Zhi,et al."Dielectric properties of (FeCoCrMnZn)3O4 high-entropy oxide at high pressure".CERAMICS INTERNATIONAL 49.20(2023):32521-32527.
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