Refinement of the alpha-beta quartz phase boundary based on in situ Raman spectroscopy measurements in hydrothermal diamond-anvil cell and an evaluated equation of state of pure H2O
Li, Shenghu1,2; Chou, I-Ming2
刊名JOURNAL OF RAMAN SPECTROSCOPY
2022-05-03
卷号1页码:12
关键词hydrothermal diamond-anvil cell laser confocal micro-Raman spectroscopy equation of state alpha-beta quartz phase transition
ISSN号0377-0486
DOI10.1002/jrs.6367
通讯作者Chou, I-Ming
英文摘要

In this study, we determined the alpha-beta quartz phase transition temperatures (T(tr)s; up to similar to 924 degrees C for a total of 23 obtained under 0.1 MPa and elevated pressures) in a hydrothermal diamond-anvil cell (HDAC) at H2O pressures up to similar to 1310 MPa by using in situ Raman spectroscopy. When compared with the commonly used alpha-quartz Raman band near 465 cm(-1 )(at 24 degrees C and 0.1 MPa), the one near 128 cm(-1) is much more sensitive for detecting T-tr. The corresponding phase transition pressure (P-tr) at each measured T-tr was calculated from three equations of state (EoS) of pure H2O. The corresponding three alpha-beta quartz phase boundaries were compared with those derived from previous experimental results. The best fitted one can be represented by: P-tr (+/- 5.6 MPa) = 0.0008.T-tr(2) + 2.8056.T-tr - 1877.5, where 574 degrees C <= (tr) <= 889 degrees C with R-2 = 0.9998. Our results agree, within experimental uncertainties, with most of previous experimental data, and our newly determined alpha-beta quartz P-tr-T-tr phase boundary can be used as a reliable pressure calibrant in HDAC. Furthermore, the experimental procedures used in this study, including the use of Raman spectroscopy criterion for T-tr determination, can be easily applied to obtain improved EoS of geologically important aqueous solutions containing salt(s) at pressure-temperature conditions up to similar to 1.2 GPa-900 degrees C.

资助项目Hadal-trench Research Program[XDB06060100] ; Key Frontier Science Program of Chinese Academy of Sciences[QYZDY-SSW-DQC008] ; Knowledge Innovation Program[SIDSSE-201302] ; National Key Research and Development Program of China[2016YFC0600606] ; Shandong Provincial Natural Science Foundation[ZR2020QD029]
WOS关键词PRESSURE ; TRANSITION ; INVERSION ; WATER
WOS研究方向Spectroscopy
语种英语
出版者WILEY
WOS记录号WOS:000789781500001
资助机构Hadal-trench Research Program ; Key Frontier Science Program of Chinese Academy of Sciences ; Knowledge Innovation Program ; National Key Research and Development Program of China ; Shandong Provincial Natural Science Foundation
内容类型期刊论文
源URL[http://ir.idsse.ac.cn/handle/183446/9482]  
专题深海科学研究部_深海极端环境模拟研究实验室
通讯作者Chou, I-Ming
作者单位1.Shandong Inst Geol Sci, Key Lab Gold Mineralizat Proc & Resource Utilizat, MNR, Shandong Prov Key Lab Metallogen Geol Proc & Reso, Jinan, Peoples R China
2.Chinese Acad Sci, Inst Deep Sea Sci & Engn, CAS Key Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Hainan, Peoples R China
推荐引用方式
GB/T 7714
Li, Shenghu,Chou, I-Ming. Refinement of the alpha-beta quartz phase boundary based on in situ Raman spectroscopy measurements in hydrothermal diamond-anvil cell and an evaluated equation of state of pure H2O[J]. JOURNAL OF RAMAN SPECTROSCOPY,2022,1:12.
APA Li, Shenghu,&Chou, I-Ming.(2022).Refinement of the alpha-beta quartz phase boundary based on in situ Raman spectroscopy measurements in hydrothermal diamond-anvil cell and an evaluated equation of state of pure H2O.JOURNAL OF RAMAN SPECTROSCOPY,1,12.
MLA Li, Shenghu,et al."Refinement of the alpha-beta quartz phase boundary based on in situ Raman spectroscopy measurements in hydrothermal diamond-anvil cell and an evaluated equation of state of pure H2O".JOURNAL OF RAMAN SPECTROSCOPY 1(2022):12.
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