Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets

doi:10.1021/acs.jpcc.2c00531

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	Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets
	Y. Zhang; L. X. Wang; G. C. Zheng; S. Y. Lyu; Y. Zhang and K. A. Chang
刊名	Journal of Physical Chemistry C
	2022
卷号	126 期号:27 页码:11129-11137
ISSN号	1932-7447
DOI	10.1021/acs.jpcc.2c00531
英文摘要	ABSTRACT: In this article, we address subnanometer resolved fluorescence imaging of single molecule inside a plasmonic picocavity by proposing a semiclassical theory via combining the macroscopic quantum electrodynamics theory and the open quantum system theory. To gain insights into the experimental 020-0677-y], we have further equipped this theory with the classical electromagnetic simulation of the picocavity, formed by atomistic cluster-decorated silver STM tip and a silver substrate, and the time-dependent density functional theory calculation of zinc phthalocyanine molecule. Our simulations not only reproduce the fluorescence spectrum and imaging as measured in the experiment, confirming the influence of extreme field confinement afforded by the picocavity, but also predict Rabi oscillation dynamics and Mollow triplets spectrum for moderate laser excitation. Thus, our study highlights the possibility of coherently manipulating the molecular state and exploring quantum optical phenomena with the plasmonic picocavity.
URL标识	查看原文
语种	英语
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/66990]
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	Y. Zhang,L. X. Wang,G. C. Zheng,et al. Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets[J]. Journal of Physical Chemistry C,2022,126(27):11129-11137.
APA	Y. Zhang,L. X. Wang,G. C. Zheng,S. Y. Lyu,&Y. Zhang and K. A. Chang.(2022).Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets.Journal of Physical Chemistry C,126(27),11129-11137.
MLA	Y. Zhang,et al."Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets".Journal of Physical Chemistry C 126.27(2022):11129-11137.