Sulfur Vacancies-Triggered High SERS Activity of Molybdenum Disulfide for Ultrasensitive Detection of Trace Diclofenac

doi:10.1002/adom.202201395

	Sulfur Vacancies-Triggered High SERS Activity of Molybdenum Disulfide for Ultrasensitive Detection of Trace Diclofenac
	Quan, Yingnan 1,2,3; Tang, Xiang-Hu 1,2; Shen, Wei 2; Li, Peihua 1,2,3; Yang, Meng 1,2,3; Huang, Xing-Jiu 1,2,3; Liu, Wen-Qing 1,2,3
刊名	ADVANCED OPTICAL MATERIALS
	2022-09-01
关键词	antibiotic contaminant diclofenac nanostructured molybdenum disulfide surface-enhanced Raman scattering sulfur vacancies
ISSN号	2195-1071
DOI	10.1002/adom.202201395
通讯作者	Tang, Xiang-Hu(tangxh2011@iim.ac.cn) ; Huang, Xing-Jiu(xingjiuhuang@iim.ac.cn) ; Liu, Wen-Qing(wqliu@aiofm.ac.cn)
英文摘要	Due to the efficient photoinduced charge transfer properties of nonmetals, nonmetallic surface-enhanced Raman scattering (SERS) substrates have been advanced rapidly these years. And among of these, molybdenum disulfide (MoS2) is perceived as one of the most representative nonmetallic SERS substrates due to its abundant active sites. However, its progress in SERS field is severely hindered because of the lower SERS activity. Herein, one type of vacancies-triggered highly sensitive SERS substrate based on nanostructured MoS2 with sulfur vacancies (V-S) is proposed. The V-S-MoS2 substrates are intended to promote the SERS performance through the V-S density regulation. Intrinsically, moderate V-S can change the bandgap structure of MoS2, thus promoting the separation of internal carriers and enhancing the interaction with target species. Externally, the presence of V-S can bring abundant adsorption sites on MoS2 surface, which greatly improves its ability to enrich target molecules. Both internal and external properties make V-S-MoS2 a high SERS activity substrate. Moreover, with the antibiotic contaminant diclofenac as a model probe molecule, the V-S-MoS2 substrate can accurately perceive its nanomolar concentration level with an enhancement factor up to 5.85 x 10(3). This work demonstrates exciting potential for analysis in real water environments based on nonmetallic SERS applications.
资助项目	National Key R&D Program of China[2021YFB3201400] ; National Science Foundation of China[61875206] ; Presidential Foundation of Hefei Institutes of Physical Science, Chinese Academy of Sciences[YZJJZX202019]
WOS关键词	ENHANCED RAMAN-SCATTERING ; MOS2
WOS研究方向	Materials Science ; Optics
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000848444100001
资助机构	National Key R&D Program of China ; National Science Foundation of China ; Presidential Foundation of Hefei Institutes of Physical Science, Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/131876]
专题	中国科学院合肥物质科学研究院
通讯作者	Tang, Xiang-Hu; Huang, Xing-Jiu; Liu, Wen-Qing
作者单位	1.Univ Sci & Technol China, Hefei 230031, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, HFIPS, Hefei 230031, Peoples R China 3.Chinese Acad Sci, Key Lab Environm Opt & Technol, HFIPS, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Quan, Yingnan,Tang, Xiang-Hu,Shen, Wei,et al. Sulfur Vacancies-Triggered High SERS Activity of Molybdenum Disulfide for Ultrasensitive Detection of Trace Diclofenac[J]. ADVANCED OPTICAL MATERIALS,2022.
APA	Quan, Yingnan.,Tang, Xiang-Hu.,Shen, Wei.,Li, Peihua.,Yang, Meng.,...&Liu, Wen-Qing.(2022).Sulfur Vacancies-Triggered High SERS Activity of Molybdenum Disulfide for Ultrasensitive Detection of Trace Diclofenac.ADVANCED OPTICAL MATERIALS.
MLA	Quan, Yingnan,et al."Sulfur Vacancies-Triggered High SERS Activity of Molybdenum Disulfide for Ultrasensitive Detection of Trace Diclofenac".ADVANCED OPTICAL MATERIALS (2022).