Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance | |
Guo Yujing1,2; Bao Haoming1; Fu Hao1,2; Zhang Hongwen1; Li Wenhong3; Cai Weiping1,2 | |
刊名 | ACTA METALLURGICA SINICA |
2022-06-11 | |
卷号 | 58 |
关键词 | rubidium nanoparticle sol ultrasonic emulsification ignition performance |
ISSN号 | 0412-1961 |
DOI | 10.11900/0412.1961.2021.00001 |
通讯作者 | Bao Haoming(baohm@issp.ac.cn) |
英文摘要 | Metallic rubidium (Rb) has great potential in various fields, such as energy, catalysis, and medical treatment. Fragmenting bulk Rb to the nanoscale is essential for its efficient application in these fields. However, as an alkali metal with a high chemical activity, Rb reacts violently with trace water, oxygen, and others; thus, preparing nanosized Rb is challenging. This study proposes a sample solid-liquid transformation and ultrasonic dispersion method to prepare Rb nanoparticles (NPs) utilizing Rb.. s low melting point. This method uses the ultrasonic emulsification of liquid Rb in a specific liquid (toluene) to form a colloidal Rb solution. Typically prepared Rb NPs are nearly spherical with an average size of approximately 45 nm. Further, the average size increases with a decrease in ultrasonic power. When the ultrasonic power falls to 320 and 240 W, the average NP size rises to 55 and 70 nm, respectively, demonstrating good controllability of the proposed method. Further experiments demonstrated that Rb NPs can ignite toluene at relatively low temperatures (say 120 degrees C) within 1 s. When the temperature is up to 250 degrees C, toluene can be ignited in 0.25 s. This study not only provides a new method for synthesizing Rb NPs but also offers new opportunities for novel energy-containing materials and ignition devices. |
资助项目 | Key Research and Development Project of Hebei Province[19211002D] |
WOS关键词 | DESIGN |
WOS研究方向 | Metallurgy & Metallurgical Engineering |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000799262400007 |
资助机构 | Key Research and Development Project of Hebei Province |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/131093] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Bao Haoming |
作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Grad Sch Sci Isl, Hefei 230026, Peoples R China 3.Hebei Rubidium Cesium Technol Co Ltd, Chengde 063000, Peoples R China |
推荐引用方式 GB/T 7714 | Guo Yujing,Bao Haoming,Fu Hao,et al. Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance[J]. ACTA METALLURGICA SINICA,2022,58. |
APA | Guo Yujing,Bao Haoming,Fu Hao,Zhang Hongwen,Li Wenhong,&Cai Weiping.(2022).Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance.ACTA METALLURGICA SINICA,58. |
MLA | Guo Yujing,et al."Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance".ACTA METALLURGICA SINICA 58(2022). |
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