Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance
Guo Yujing1,2; Bao Haoming1; Fu Hao1,2; Zhang Hongwen1; Li Wenhong3; Cai Weiping1,2
刊名ACTA METALLURGICA SINICA
2022-06-11
卷号58
关键词rubidium nanoparticle sol ultrasonic emulsification ignition performance
ISSN号0412-1961
DOI10.11900/0412.1961.2021.00001
通讯作者Bao Haoming(baohm@issp.ac.cn)
英文摘要Metallic rubidium (Rb) has great potential in various fields, such as energy, catalysis, and medical treatment. Fragmenting bulk Rb to the nanoscale is essential for its efficient application in these fields. However, as an alkali metal with a high chemical activity, Rb reacts violently with trace water, oxygen, and others; thus, preparing nanosized Rb is challenging. This study proposes a sample solid-liquid transformation and ultrasonic dispersion method to prepare Rb nanoparticles (NPs) utilizing Rb.. s low melting point. This method uses the ultrasonic emulsification of liquid Rb in a specific liquid (toluene) to form a colloidal Rb solution. Typically prepared Rb NPs are nearly spherical with an average size of approximately 45 nm. Further, the average size increases with a decrease in ultrasonic power. When the ultrasonic power falls to 320 and 240 W, the average NP size rises to 55 and 70 nm, respectively, demonstrating good controllability of the proposed method. Further experiments demonstrated that Rb NPs can ignite toluene at relatively low temperatures (say 120 degrees C) within 1 s. When the temperature is up to 250 degrees C, toluene can be ignited in 0.25 s. This study not only provides a new method for synthesizing Rb NPs but also offers new opportunities for novel energy-containing materials and ignition devices.
资助项目Key Research and Development Project of Hebei Province[19211002D]
WOS关键词DESIGN
WOS研究方向Metallurgy & Metallurgical Engineering
语种英语
出版者SCIENCE PRESS
WOS记录号WOS:000799262400007
资助机构Key Research and Development Project of Hebei Province
内容类型期刊论文
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/131093]  
专题中国科学院合肥物质科学研究院
通讯作者Bao Haoming
作者单位1.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Hefei 230031, Peoples R China
2.Univ Sci & Technol China, Grad Sch Sci Isl, Hefei 230026, Peoples R China
3.Hebei Rubidium Cesium Technol Co Ltd, Chengde 063000, Peoples R China
推荐引用方式
GB/T 7714
Guo Yujing,Bao Haoming,Fu Hao,et al. Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance[J]. ACTA METALLURGICA SINICA,2022,58.
APA Guo Yujing,Bao Haoming,Fu Hao,Zhang Hongwen,Li Wenhong,&Cai Weiping.(2022).Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance.ACTA METALLURGICA SINICA,58.
MLA Guo Yujing,et al."Ultrasonic Emulsification Preparation of Metallic Rubidium Sol and Its Ignition Performance".ACTA METALLURGICA SINICA 58(2022).
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