Small molecule-assisted synthesis of carbon supported platinum intermetallic fuel cell catalysts

doi:10.1038/s41467-022-34037-7

	Small molecule-assisted synthesis of carbon supported platinum intermetallic fuel cell catalysts
	Song, Tian-Wei 6; Xu, Cong 6; Sheng, Zhu-Tao 4; Yan, Hui-Kun 6; Tong, Lei 6; Liu, Jun 1,5; Zeng, Wei-Jie 6; Zuo, Lu-Jie 6; Yin, Peng 6; Zuo, Ming 6
刊名	NATURE COMMUNICATIONS
	2022-10-31
卷号	13
DOI	10.1038/s41467-022-34037-7
通讯作者	Liang, Hai-Wei(hwliang@ustc.edu.cn)
英文摘要	Supported ordered intermetallic compounds exhibit superior catalytic performance over their disordered alloy counterparts in diverse reactions. But the synthesis of intermetallic compounds catalysts often requires high-temperature annealing that leads to the sintering of metals into larger crystallites. Herein, we report a small molecule-assisted impregnation approach to realize the general synthesis of a family of intermetallic catalysts, consisting of 18 binary platinum intermetallic compounds supported on carbon blacks. The molecular additives containing heteroatoms (that is, O, N, or S) can be coordinated with platinum in impregnation and thermally converted into heteroatom-doped graphene layers in high-temperature annealing, which significantly suppress alloy sintering and insure the formation of small-sized intermetallic catalysts. The prepared optimal PtCo intermetallics as cathodic oxygen-reduction catalysts exhibit a high mass activity of 1.08 A mg(Pt)(-1) at 0.9 V in H-2-O-2 fuel cells and a rated power density of 1.17 W cm(-2) in H-2-air fuel cells. Synthesis of small sized Pt intermetallic catalysts remains challenging. Herewith authors prepared 18 binary Pt intermetallic compounds with small particle size by molecule-assisted synthesis strategy to in-situ form the heteroatom-doped carbon shell.
资助项目	National Key Research and Development Program of China[2018YFA0702001] ; National Natural Science Foundation of China[22071225] ; National Natural Science Foundation of China[51971211] ; Plan for Anhui Major Provincial Science & Technology Project[202203a0520013] ; Plan for Anhui Major Provincial Science & Technology Project[202103a05020015] ; Fundamental Research Funds for the Central Universities[WK2060190103] ; Hefei National Synchrotron Radiation Laboratory[KY2060000175] ; Collaborative Innovation Program of Hefei Science Center of CAS[2021HSC-CIP015] ; Youth Innovation Promotion Association of CAS[2017483]
WOS关键词	OXYGEN REDUCTION REACTION ; CATHODE CATALYSTS ; NANOPARTICLES ; PERFORMANCE ; STABILITY ; DESIGN
WOS研究方向	Science & Technology - Other Topics
语种	英语
出版者	NATURE PORTFOLIO
WOS记录号	WOS:000877943100010
资助机构	National Key Research and Development Program of China ; National Natural Science Foundation of China ; Plan for Anhui Major Provincial Science & Technology Project ; Fundamental Research Funds for the Central Universities ; Hefei National Synchrotron Radiation Laboratory ; Collaborative Innovation Program of Hefei Science Center of CAS ; Youth Innovation Promotion Association of CAS
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/130146]
专题	中国科学院合肥物质科学研究院
通讯作者	Liang, Hai-Wei
作者单位	1.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Solid State Phys, Hefei 230031, Peoples R China 2.Anhui Univ, Sch Chem & Chem Engn, Hefei 230601, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China 4.Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241000, Peoples R China 5.Anhui Contango New Energy Technol Co Ltd, Hefei 230088, Peoples R China 6.Univ Sci & Technol China, Hefei Natl Res Ctr Phys Sci Microscale, Dept Chem, Hefei 230026, Peoples R China
推荐引用方式 GB/T 7714	Song, Tian-Wei,Xu, Cong,Sheng, Zhu-Tao,et al. Small molecule-assisted synthesis of carbon supported platinum intermetallic fuel cell catalysts[J]. NATURE COMMUNICATIONS,2022,13.
APA	Song, Tian-Wei.,Xu, Cong.,Sheng, Zhu-Tao.,Yan, Hui-Kun.,Tong, Lei.,...&Liang, Hai-Wei.(2022).Small molecule-assisted synthesis of carbon supported platinum intermetallic fuel cell catalysts.NATURE COMMUNICATIONS,13.
MLA	Song, Tian-Wei,et al."Small molecule-assisted synthesis of carbon supported platinum intermetallic fuel cell catalysts".NATURE COMMUNICATIONS 13(2022).