Tandem radical cyclization to construct poly-brominated 2-oxindoles | |
Chen, Fengjuan1; Wang, Yajun1; Zhao, Shijun2; Jiang, Wei1; Huo, Congde1 | |
刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY |
2017-09-28 | |
卷号 | 15期号:36页码:7710-7714 |
ISSN号 | 1477-0520 |
DOI | 10.1039/c7ob01859b |
英文摘要 | Catalytic amounts of TBHP (15 mol%) promoted tribromomethylation of activated alkenes has been developed. This method provided a metal-free aerobic way to construct tribromomethylated 2-oxindoles from the reaction of readily available N-arylacrylamides with CBr4 via a proposed tandem radical cyclization process. Air is used as an efficient terminal oxidant in this transformation. The formation of 1,1-dibromo-olefin derivatives was also realized at higher temperature under neat conditions. |
资助项目 | Fok Ying Tong Education Foundation[141116] |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000411463200030 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/33095] |
专题 | 外国语学院 |
通讯作者 | Huo, Congde |
作者单位 | 1.Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China 2.Lanzhou Univ Technol, Coll Foreign Languages, Lanzhou 730050, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Fengjuan,Wang, Yajun,Zhao, Shijun,et al. Tandem radical cyclization to construct poly-brominated 2-oxindoles[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2017,15(36):7710-7714. |
APA | Chen, Fengjuan,Wang, Yajun,Zhao, Shijun,Jiang, Wei,&Huo, Congde.(2017).Tandem radical cyclization to construct poly-brominated 2-oxindoles.ORGANIC & BIOMOLECULAR CHEMISTRY,15(36),7710-7714. |
MLA | Chen, Fengjuan,et al."Tandem radical cyclization to construct poly-brominated 2-oxindoles".ORGANIC & BIOMOLECULAR CHEMISTRY 15.36(2017):7710-7714. |
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