Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances | |
Gao, Huajing2,3; Tang, Shengnan2; Chen, Xiangyu2; Yu, Chuan2; Wang, Shifa1,2,4; Fang, Leiming4; Yu, Xianlun2; Zhao, Xinxin2; Sun, Guangzhuang2; Yang, Hua3 | |
刊名 | RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A |
2021-12-01 | |
卷号 | 95期号:SUPPL 2页码:S288-S295 |
关键词 | CoWO4 sintering temperature optical properties emission band blue light emission supercapacitor |
ISSN号 | 0036-0244 |
DOI | 10.1134/S0036024421150103 |
英文摘要 | The present study reports the gamma-ray irradiation assisted polyacrylamide gel synthesis and optical, photoluminescence and supercapacitive performances of cobalt tungstates with special defect structure. The analysis of X-ray powder diffraction data showed that the purity and crystallinity of CoWO4 increased with the increasing of sintering temperature. X-ray photoelectron spectroscopy and energy spectrum analysis show that the high purity CoWO4 powders does not contain any other impurities. Color and optical properties analysis indicates that the high purity CoWO4 powders exhibits a strongest blue color than that of other samples. The photoluminescence spectrum shows three obvious emission bands in ultraviolet (340-375 nm), blue (424-490 nm), and green light emission (510 nm) regions under 220 nm xenon lamp excitation, which are ascribed to the organic impurities, the transition of T-3(1u) levels to the (1)A(1g) level, and the partially allowed transition of T-1g to (1)A(1g), respectively. Studies on electrochemical properties demonstrate that the CoWO4 powder has an excellent prospect in the supercapacitors for advanced electrochemical energy storage applications. |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | MAIK NAUKA/INTERPERIODICA/SPRINGER |
WOS记录号 | WOS:000742667400012 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/154962] |
专题 | 理学院 |
作者单位 | 1.Chongqing Three Gorges Univ, Chongqing Key Lab Geol Environm Monitoring & Disa, Chongqing 404000, Wanzhou, Peoples R China; 2.Chongqing Three Gorges Univ, Sch Elect & Informat Engn, Chongqing 404000, Wanzhou, Peoples R China; 3.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Peoples R China; 4.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China |
推荐引用方式 GB/T 7714 | Gao, Huajing,Tang, Shengnan,Chen, Xiangyu,et al. Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,2021,95(SUPPL 2):S288-S295. |
APA | Gao, Huajing.,Tang, Shengnan.,Chen, Xiangyu.,Yu, Chuan.,Wang, Shifa.,...&Yang, Hua.(2021).Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances.RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,95(SUPPL 2),S288-S295. |
MLA | Gao, Huajing,et al."Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances".RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A 95.SUPPL 2(2021):S288-S295. |
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