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Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances
Gao, Huajing2,3; Tang, Shengnan2; Chen, Xiangyu2; Yu, Chuan2; Wang, Shifa1,2,4; Fang, Leiming4; Yu, Xianlun2; Zhao, Xinxin2; Sun, Guangzhuang2; Yang, Hua3
刊名RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
2021-12-01
卷号95期号:SUPPL 2页码:S288-S295
关键词CoWO4 sintering temperature optical properties emission band blue light emission supercapacitor
ISSN号0036-0244
DOI10.1134/S0036024421150103
英文摘要The present study reports the gamma-ray irradiation assisted polyacrylamide gel synthesis and optical, photoluminescence and supercapacitive performances of cobalt tungstates with special defect structure. The analysis of X-ray powder diffraction data showed that the purity and crystallinity of CoWO4 increased with the increasing of sintering temperature. X-ray photoelectron spectroscopy and energy spectrum analysis show that the high purity CoWO4 powders does not contain any other impurities. Color and optical properties analysis indicates that the high purity CoWO4 powders exhibits a strongest blue color than that of other samples. The photoluminescence spectrum shows three obvious emission bands in ultraviolet (340-375 nm), blue (424-490 nm), and green light emission (510 nm) regions under 220 nm xenon lamp excitation, which are ascribed to the organic impurities, the transition of T-3(1u) levels to the (1)A(1g) level, and the partially allowed transition of T-1g to (1)A(1g), respectively. Studies on electrochemical properties demonstrate that the CoWO4 powder has an excellent prospect in the supercapacitors for advanced electrochemical energy storage applications.
WOS研究方向Chemistry
语种英语
出版者MAIK NAUKA/INTERPERIODICA/SPRINGER
WOS记录号WOS:000742667400012
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/154962]  
专题理学院
作者单位1.Chongqing Three Gorges Univ, Chongqing Key Lab Geol Environm Monitoring & Disa, Chongqing 404000, Wanzhou, Peoples R China;
2.Chongqing Three Gorges Univ, Sch Elect & Informat Engn, Chongqing 404000, Wanzhou, Peoples R China;
3.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Peoples R China;
4.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China
推荐引用方式
GB/T 7714
Gao, Huajing,Tang, Shengnan,Chen, Xiangyu,et al. Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,2021,95(SUPPL 2):S288-S295.
APA Gao, Huajing.,Tang, Shengnan.,Chen, Xiangyu.,Yu, Chuan.,Wang, Shifa.,...&Yang, Hua.(2021).Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances.RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,95(SUPPL 2),S288-S295.
MLA Gao, Huajing,et al."Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances".RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A 95.SUPPL 2(2021):S288-S295.
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