Optical and electrochemical properties of perovskite type MAlO3 (M=Y, La, Ce) pigments synthesized by a gamma-ray irradiation assisted polyacrylamide gel route

doi:10.1016/j.ceramint.2018.05.105

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	Optical and electrochemical properties of perovskite type MAlO3 (M=Y, La, Ce) pigments synthesized by a gamma-ray irradiation assisted polyacrylamide gel route
	Gao, Huajing 1,4; Yang, Hua 1,4; Wang, Shifa 2,3; Zhao, XinXin 1,4
刊名	Ceramics International
	2018-08-15
卷号	44 期号:12 页码:14754-14766
关键词	Aluminum compounds Cerium Electrochemical impedance spectroscopy Electrochemical properties Enamels Energy gap Field emission microscopes Fluorescence Fluorescence spectroscopy Gamma rays High resolution transmission electron microscopy Irradiation Metal ions Morphology Optical emission spectroscopy Particle size Perovskite Photoluminescence Scanning electron microscopy Surface morphology Crystallization temperature Excitation wavelength Field emission scanning electron microscopy Gamma-ray irradiation Photoluminescence properties Polyacrylamide gel routes Synthesis conditions Trivalent metal ions
ISSN号	02728842
DOI	10.1016/j.ceramint.2018.05.105
英文摘要	Perovskite type MAlO3 (M=Y, La, Ce) pigments with different phases were successfully prepared by a gamma-ray irradiation assisted polyacrylamide gel route under the same synthesis conditions and their phase purity, surface morphology, and color, optical, photoluminescence and electrochemical properties were characterized by X-ray diffraction (XRD), UV–visible spectroscopy (UV–Vis), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), fluorescence spectroscopy (FS), and electrochemical impedance spectroscopy (EIS). The effects of crystallization temperature and trivalent metal ion M3+ on the physico-chemical properties of MAlO3 (M=Y, La, Ce) pigments were systematically investigated. The crystallization temperature of MAlO3 pigments decreases with the increasing ion radius of trivalent metal ions M3+. The synthetic route produced nanosized or porous powders, in addition, no direct relationship was resulted between particle size or energy band gap (Eg) value of MAlO3 pigments with trivalent metal ions M3+. Among all, CeAlO3 and YAlO3: Ce pigments exhibited excellent photoluminescence properties, in which the emission peaks at 378, 429, 468 and 480 nm with the excitation wavelength at 280 nm and the emission peaks at 369, 413 and 458 nm with the excitation wavelength at 270 nm, respectively. The fluorescence mechanism of the CeAlO3 and YAlO3: Ce pigments were studied based on previous reports and the experimental results. The color and electrochemical properties of MAlO3 pigments change appears to be highly dependent on the trivalent metal ions M3+. Moreover, the results demonstrated that doping Ce3+ ions into YAlO3 precursor solution dropped crystallization temperature and improved phase purity, photoluminescence, and electrochemical properties of YAlO3 pigment. © 2018 Elsevier Ltd and Techna Group S.r.l.
WOS研究方向	Materials Science
语种	英语
出版者	Elsevier Ltd
WOS记录号	WOS:000437077000176
内容类型	期刊论文
源URL	[http://ir.lut.edu.cn/handle/2XXMBERH/114857]
专题	理学院
作者单位	1.State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou; 730050, China; 2.Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Sichuan; Mianyang; 621900, China 3.Science and Technology on Vacuum Technology and Physics Laboratory, Lanzhou Institute of Physics, Gansu, Lanzhou; 730000, China; 4.School of Science, Lanzhou University of Technology, Lanzhou; 730050, China;
推荐引用方式 GB/T 7714	Gao, Huajing,Yang, Hua,Wang, Shifa,et al. Optical and electrochemical properties of perovskite type MAlO3 (M=Y, La, Ce) pigments synthesized by a gamma-ray irradiation assisted polyacrylamide gel route[J]. Ceramics International,2018,44(12):14754-14766.
APA	Gao, Huajing,Yang, Hua,Wang, Shifa,&Zhao, XinXin.(2018).Optical and electrochemical properties of perovskite type MAlO3 (M=Y, La, Ce) pigments synthesized by a gamma-ray irradiation assisted polyacrylamide gel route.Ceramics International,44(12),14754-14766.
MLA	Gao, Huajing,et al."Optical and electrochemical properties of perovskite type MAlO3 (M=Y, La, Ce) pigments synthesized by a gamma-ray irradiation assisted polyacrylamide gel route".Ceramics International 44.12(2018):14754-14766.