Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties

doi:10.1002/pat.4784

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	Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties
	Yang, Baoping; Wang, Lurong; Guo, Yongliang; Zhang, Yabin; Wang, Niannian; Cui, Jinfeng; Guo, Junhong; Tian, Li
刊名	Polymers for Advanced Technologies
	2020-03-01
卷号	31 期号:3 页码:472-481
关键词	Acrylic monomers Calorimeters Copolymerization Differential scanning calorimetry Esters Transparency Ultraviolet visible spectroscopy Differential scanning calorimeters Flame retardancy Flame retardant properties Limited oxygen index Methyl methacrylates Peak heat release rates Poly(methyl methacrylate) (PMMA) Radical copolymerization
ISSN号	10427147
DOI	10.1002/pat.4784
英文摘要	A novel poly(methyl methacrylate) (PMMA)-based copolymer (PMMA-co-BDPA) rich in aromatic rings was synthesized via radical copolymerization between a phosphorus-containing acrylic monomer (BDPA) and methyl methacrylate (MMA). UV-vis spectroscopy demonstrated that the copolymer had high transparency. Thermogravimetric analysis (TGA) and a differential scanning calorimeter (DSC) were used to test the thermal properties of the composites. Additionally, the PMMA-co-BDPA-15 copolymer exhibited a 23% increase in the limited oxygen index (LOI) value. A cone calorimeter test indicated that the peak heat release rate (pk-HRR) of PMMA-co-BDPA was reduced by 29.2% compared with that of pure PMMA, and the carbon yield of burning was obviously increased. The combined test results demonstrated that the prepared copolymer material had good transparency, thermal stability, and flame retardancy. © 2019 John Wiley & Sons, Ltd.
WOS研究方向	Polymer Science
语种	英语
出版者	John Wiley and Sons Ltd
WOS记录号	WOS:000500369800001
内容类型	期刊论文
源URL	[http://ir.lut.edu.cn/handle/2XXMBERH/150809]
专题	图书馆石油化工学院实验室建设与管理处
作者单位	College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou, China
推荐引用方式 GB/T 7714	Yang, Baoping,Wang, Lurong,Guo, Yongliang,et al. Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties[J]. Polymers for Advanced Technologies,2020,31(3):472-481.
APA	Yang, Baoping.,Wang, Lurong.,Guo, Yongliang.,Zhang, Yabin.,Wang, Niannian.,...&Tian, Li.(2020).Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties.Polymers for Advanced Technologies,31(3),472-481.
MLA	Yang, Baoping,et al."Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties".Polymers for Advanced Technologies 31.3(2020):472-481.