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Facile solid−phase synthesis of layered NiS/rGO nanocomposite for high−performance hybrid supercapacitor
Zhang, Deyi1,2; Gao, Shiyao1,2; Zhang, Jiwei1,2; Wang, Jingruo1,2; She, Wenna1,2; Wang, Kunjie1,2; Xia, Xu2; Yang, Biao2; Meng, Xianxin2
刊名Journal of Power Sources
2021-12-01
卷号514
关键词Nickel sulfates Porous materials Sulfur compounds Supercapacitor Transition metals Hybrid supercapacitors Layered NiS/rGO nanocomposite Layered Structures Liquid-phase synthesis Performance Solid phase synthesis Synthesis method Synthesis route Thermal Transition metal sulfides
ISSN号03787753
DOI10.1016/j.jpowsour.2021.230590
英文摘要Generally, transition metal sulfides and their composites are prepared by tedious and uneconomical liquid−phase synthesis methods. In this work, we developed a facile solid−phase synthesis route for preparing NiS/rGO nanocomposite by thermal treating a ternary solid mixture of nickel formate, elemental sulfur and GO in an autoclave under ambient atmosphere. The prepared nanocomposite exhibits a loose layered structure, spherical or ellipsoidal NiS nanoparticles with a size of 20–100 nm disperse on the well−separated rGO nanosheets. Due to the unique layered structure, the obtained NiS/rGO nanocomposite exhibits an ultrahigh specific capacity of 299.7 mAh g−1 (2157.8 F g−1) at a current density of 2 A g−1 and good rate capacity (161.2 mAh g−1 at 15 A g−1). The hybrid supercapacitor device based on the layered NiS/rGO nanocomposite and an interconnected hierarchical porous carbon delivers a high specific energy of 56.1 Wh kg−1 at a specific power of 880 W kg−1 while exhibits a high capacity retention of 92.4% after 30,000 charge/discharge cycles, demonstrating the promising potential of the developed solid−phase synthesis route for the preparation of NiS/rGO nanocomposites using for high−performance hybrid supercapacitor. © 2021
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
语种英语
出版者Elsevier B.V.
WOS记录号WOS:000709720200002
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/150697]  
专题石油化工学院
作者单位1.Key Laboratory of Low−Carbon Energy and Chemical Engineering of Gansu Province, Lanzhou University of Technology, Lanzhou; 730050, China;
2.College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou; 730050, China
推荐引用方式
GB/T 7714
Zhang, Deyi,Gao, Shiyao,Zhang, Jiwei,et al. Facile solid−phase synthesis of layered NiS/rGO nanocomposite for high−performance hybrid supercapacitor[J]. Journal of Power Sources,2021,514.
APA Zhang, Deyi.,Gao, Shiyao.,Zhang, Jiwei.,Wang, Jingruo.,She, Wenna.,...&Meng, Xianxin.(2021).Facile solid−phase synthesis of layered NiS/rGO nanocomposite for high−performance hybrid supercapacitor.Journal of Power Sources,514.
MLA Zhang, Deyi,et al."Facile solid−phase synthesis of layered NiS/rGO nanocomposite for high−performance hybrid supercapacitor".Journal of Power Sources 514(2021).
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