Preparation of 4-Methylaniline Reduced Graphene Oxide/Polyaniline Composite by One-pot Method: The Effect of Aniline Amount on the Microstructure and Electrochemical Performance | |
Chen, Nali1,2,3; Zhang, Feifei3; Ren, Yapeng3; L., Tan; H., Feng; Y., Luo | |
刊名 | Polymer Composites
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2019 | |
卷号 | 40页码:E877-E885 |
关键词 | Capacitance Graphene Microstructure Nanostructures Plastic products Polyaniline Reduced Graphene Oxide Cycling stability Electrochemical performance In-situ polymerization Layer-like structures One-pot synthesis Polyanilines (PAni) Rate performance Specific capacitance |
ISSN号 | 02728397 |
DOI | 10.1002/pc.25074 |
英文摘要 | In this study, reduced graphene oxide (GO)/polyaniline composites (GP) were successfully fabricated through a novel one-pot synthesis route with 4-methylaniline as a reductant for GO followed by in-situ polymerization of aniline. The results of X-ray diffraction and Raman spectroscopy revealed that GO was successfully reduced by 4-methylaniline. Meanwhile, the effect of aniline amount on the microstructure and electrochemical performance of the as-prepared GP was optimized by tuning the feed ratios of aniline to GO. The results demonstrated that the feed ratio of aniline to GO played a very significant role in constructing the nano-structure of GP, and furthermore determined their electrochemical performance. GP displayed a layer-like structure evenly covered by polyaniline (PANI) nanowires with the feed ratio of aniline to GO of 30/1 (m/m). Under this condition, the composite exhibited a maximum specific capacitance of 530.4 F g−1 at a current density of 0.5 A g−1, remarkably higher than that of unitary PANI (367.9 F g−1), and showed an excellent rate performance (411.1 F g−1 at 20 A g−1) as well. Moreover, the composite delivered good cycling stability with less than 8% decrease in the specific capacitance after 2000 cycles at a scan rate of 100 mV s−1, which was a great improvement over the unitary PANI (69.1%). POLYM. COMPOS., 40:E877–E885, 2019. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers |
WOS研究方向 | Materials Science ; Polymer Science |
语种 | 英语 |
出版者 | John Wiley and Sons Inc, Postfach 10 11 61, 69451 Weinheim, Boschstrabe 12, 69469 Weinheim, Deutschland, 69469, Germany |
WOS记录号 | WOS:000459570800085 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/150490] ![]() |
专题 | 石油化工学院 |
作者单位 | 1.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, China; 2.School of Materials Science and Engineering, Lanzhou University of Technology, China; 3.College of Petrochemical Technology, Lanzhou University of Technology, China |
推荐引用方式 GB/T 7714 | Chen, Nali,Zhang, Feifei,Ren, Yapeng,et al. Preparation of 4-Methylaniline Reduced Graphene Oxide/Polyaniline Composite by One-pot Method: The Effect of Aniline Amount on the Microstructure and Electrochemical Performance[J]. Polymer Composites,2019,40:E877-E885. |
APA | Chen, Nali,Zhang, Feifei,Ren, Yapeng,L., Tan,H., Feng,&Y., Luo.(2019).Preparation of 4-Methylaniline Reduced Graphene Oxide/Polyaniline Composite by One-pot Method: The Effect of Aniline Amount on the Microstructure and Electrochemical Performance.Polymer Composites,40,E877-E885. |
MLA | Chen, Nali,et al."Preparation of 4-Methylaniline Reduced Graphene Oxide/Polyaniline Composite by One-pot Method: The Effect of Aniline Amount on the Microstructure and Electrochemical Performance".Polymer Composites 40(2019):E877-E885. |
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