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Facile solid-phase synthesis of layered NiS/rGO nanocomposite for high-performance hybrid supercapacitor
Zhang, Deyi1,2; Gao, Shiyao1,2; Zhang, Jiwei1,2; Wang, Jingruo1,2; She, Wenna1,2; Wang, Kunjie1,2; Xia, Xu2; Yang, Biao2; Meng, Xianxin2
刊名JOURNAL OF POWER SOURCES
2021-12-01
卷号514
关键词Solid-phase synthesis Layered NiS/rGO nanocomposite Hybrid supercapacitor
ISSN号0378-7753
DOI10.1016/j.jpowsour.2021.230590
英文摘要Generally, transition metal sulfides and their composites are prepared by tedious and uneconomical liquid--phasesynthesis methods. In this work, we developed a facile solid-phase synthesis route for preparing NiS/ rGO nanocomposite by thermal treating a ternary solid mixture of nickel formate, elemental sulfur and GO in an autoclave under ambient atmosphere. The prepared nanocomposite exhibits a loose layered structure, spherical or ellipsoidal NiS nanoparticles with a size of 20-100 nm disperse on the well-separated rGO nanosheets. Due to the unique layered structure, the obtained NiS/rGO nanocomposite exhibits an ultrahigh specific capacity of 299.7 mAh g(-1) (2157.8 F g(-1)) at a current density of 2 A g(-1) and good rate capacity (161.2 mAh g(-1) at 15 A g(-1)). The hybrid supercapacitor device based on the layered NiS/rGO nanocomposite and an interconnected hierarchical porous carbon delivers a high specific energy of 56.1 Wh kg(-1) at a specific power of 880 W kg(-1) while exhibits a high capacity retention of 92.4% after 30,000 charge/discharge cycles, demonstrating the promising potential of the developed solid-phase synthesis route for the preparation of NiS/rGO nano-composites using for high-performance hybrid supercapacitor.
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
语种英语
出版者ELSEVIER
WOS记录号WOS:000709720200002
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/150038]  
专题石油化工学院
作者单位1.Lanzhou Univ Technol, Key Lab Low Carbon Energy & Chem Engn Gansu Prov, Lanzhou 730050, Peoples R China;
2.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Deyi,Gao, Shiyao,Zhang, Jiwei,et al. Facile solid-phase synthesis of layered NiS/rGO nanocomposite for high-performance hybrid supercapacitor[J]. JOURNAL OF POWER SOURCES,2021,514.
APA Zhang, Deyi.,Gao, Shiyao.,Zhang, Jiwei.,Wang, Jingruo.,She, Wenna.,...&Meng, Xianxin.(2021).Facile solid-phase synthesis of layered NiS/rGO nanocomposite for high-performance hybrid supercapacitor.JOURNAL OF POWER SOURCES,514.
MLA Zhang, Deyi,et al."Facile solid-phase synthesis of layered NiS/rGO nanocomposite for high-performance hybrid supercapacitor".JOURNAL OF POWER SOURCES 514(2021).
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