Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains

doi:10.1039/d1nj00775k

CORC > 兰州理工大学 > 兰州理工大学 > 石油化工学院

	Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains
	Chen, Lan 1; He, Chunying 1; Liu, Dongmei 1; Zheng, Yi 2; Li, Wanlu 1; Zu, Yanli 1
刊名	NEW JOURNAL OF CHEMISTRY
	2021
卷号	45 期号:22 页码:10021-10030
关键词	Chlorine compounds Indium compounds Microcomputers Optical properties Alkyl chain Effective approaches NLO properties Nonlinear absorptions Physical parameters Third order nonlinear optical properties Third-order nonlinear optical Z-scan technique
ISSN号	1144-0546
DOI	10.1039/d1nj00775k
英文摘要	Increasing the electron density on the phthalocyanine (Pc) ring is an effective approach for ensuring an excellent third-order nonlinear optical (NLO) property. Herein, a series of axially substituted indium Pcs (axial substituent: ethyl, n-propyl, n-butyl, n-pentyl) were synthesized on the basis of tetra-[3-(2-ethoxy)ethoxy] indium phthalocyanine chloride (InClPc). The third-order nonlinear optical properties were investigated by the Z-scan technique at 532 nm with 4 ns laser pulses. All the axially alkyl substituted InPcs showed a better nonlinear absorption response than InClPc. The NLO properties of the axially substituted Pcs got better with the increased length of the alkyl chain. The effect of alkyl chain substituents on the nonlinear absorption of indium phthalocyanine was demonstrated through their optical physical parameters (Phi(F), k(ST), Phi(T), and tau(T)).
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000651843300001
内容类型	期刊论文
源URL	[http://ir.lut.edu.cn/handle/2XXMBERH/148239]
专题	石油化工学院
作者单位	1.Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem, Minist Educ, Harbin 150080, Peoples R China; 2.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
推荐引用方式 GB/T 7714	Chen, Lan,He, Chunying,Liu, Dongmei,et al. Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains[J]. NEW JOURNAL OF CHEMISTRY,2021,45(22):10021-10030.
APA	Chen, Lan,He, Chunying,Liu, Dongmei,Zheng, Yi,Li, Wanlu,&Zu, Yanli.(2021).Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains.NEW JOURNAL OF CHEMISTRY,45(22),10021-10030.
MLA	Chen, Lan,et al."Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains".NEW JOURNAL OF CHEMISTRY 45.22(2021):10021-10030.