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A novel coumarin-derived acylhydrazone Schiff base gelator for synthesis of organogels and identification of Fe3+
Yang, Yun-Shang; Liang, Chuan; Yang, Chen; Zhang, Ying-Peng; Wang, Bao-Xu; Liu, Jie
刊名Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
2020-08-15
卷号237
关键词Aniline Fluorescence Hydrogen bonds Van der Waals forces Fluorescence spectra Intermolecular hydrogen bonding Iso-propanols Pi-stacking Self-assemble Tert-amyl alcohols Van Der Waals interactions Visible spectroscopy
ISSN号13861425
DOI10.1016/j.saa.2020.118391
英文摘要A novel coumarin-derived acylhydrazone Schiff base fluorescent organogel (G1) was designed and synthesized. Gelator G1 can form stable organogels in isopropanol, tert-amyl alcohol, n-butanol and phenylamine. The organogel could be converted to solution by heating and the solution could be restored to gel state by cooling. The self-assemble mechanism of G1 was investigated by XRD, FT-IR and SEM techniques. The results indicated the intermolecular hydrogen bonding, Van der Waals interaction and π-π stacking are the forces for the self-assembly of the gelator to form the organogel. The optical properties of the compound were studied by UV–visible spectroscopy and fluorescence spectra. Further study presented that gelator G1 could selectively and sensitively response to Fe3+ only among tested cations. Beside the above functions, the organic gel factor G1 could also response to irradiation, heating and shaking, thus endowing the organogel with multi stimulus responsive properties. © 2020 Elsevier B.V.
WOS研究方向Spectroscopy
语种英语
出版者Elsevier B.V., Netherlands
WOS记录号WOS:000539259300014
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/115011]  
专题石油化工学院
作者单位School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou; 730050, China
推荐引用方式
GB/T 7714
Yang, Yun-Shang,Liang, Chuan,Yang, Chen,et al. A novel coumarin-derived acylhydrazone Schiff base gelator for synthesis of organogels and identification of Fe3+[J]. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy,2020,237.
APA Yang, Yun-Shang,Liang, Chuan,Yang, Chen,Zhang, Ying-Peng,Wang, Bao-Xu,&Liu, Jie.(2020).A novel coumarin-derived acylhydrazone Schiff base gelator for synthesis of organogels and identification of Fe3+.Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy,237.
MLA Yang, Yun-Shang,et al."A novel coumarin-derived acylhydrazone Schiff base gelator for synthesis of organogels and identification of Fe3+".Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 237(2020).
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