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Compatibility between LiNi0.5Mn1.5O4 and electrolyte based upon lithium bis(oxalate)borate and sulfolane for high voltage lithium-ion batteries
Li, Chunlei; Zhao, Yangyu; Zhang, Hongming; Liu, Jinliang; Jing, Jie; Cui, Xiaoling; Li, Shiyou
刊名ELECTROCHIMICA ACTA
2013-08
卷号104页码:134-139
关键词Lithium bis(oxalate)borate Sulfolane Compatibility LiNi0.5Mn1.5O4
ISSN号0013-4686
DOI10.1016/j.electacta.2013.04.075
英文摘要To seek the compatibility between LiNi0.5Mn1.5O4 and electrolyte based upon lithium bis(oxalate)borate (LiBOB) and sulfolane (SL), the electrochemical performances of 0.7 mol L-1 LiBOB-SL/DMC (1:1) electrolyte are investigated. This electrolyte has characteristic of good stability against oxidative decomposition (5.3 V. vs. Li/Li+) and satisfactory safety performance. When used in LiNi0.5Mn1.5O4/Li cells, this electrolyte exhibits several advantages, such as stable cycle performance, low cell resistance, good rate performance, and high discharge voltage plateau. It suggests that LiBOB-SL/DMC electrolyte has good compatibility with LiNi0.5Mn1.5O4 cathode, and would be an attractive electrolyte for 5V high voltage lithium-ion batteries based upon LiNi0.5Mn1.5O4 cathode. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.
资助项目Science and Technology Planning Project of Gansu Province[107RJYA056] ; Branchy Tamarisk Development Program for Young Teachers of Lanzhou University of Technology[Q201105] ; Natural Science Foundation of China[20961004]
WOS研究方向Electrochemistry
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000321601200017
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/34646]  
专题石油化工学院
通讯作者Li, Shiyou
作者单位Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Li, Chunlei,Zhao, Yangyu,Zhang, Hongming,et al. Compatibility between LiNi0.5Mn1.5O4 and electrolyte based upon lithium bis(oxalate)borate and sulfolane for high voltage lithium-ion batteries[J]. ELECTROCHIMICA ACTA,2013,104:134-139.
APA Li, Chunlei.,Zhao, Yangyu.,Zhang, Hongming.,Liu, Jinliang.,Jing, Jie.,...&Li, Shiyou.(2013).Compatibility between LiNi0.5Mn1.5O4 and electrolyte based upon lithium bis(oxalate)borate and sulfolane for high voltage lithium-ion batteries.ELECTROCHIMICA ACTA,104,134-139.
MLA Li, Chunlei,et al."Compatibility between LiNi0.5Mn1.5O4 and electrolyte based upon lithium bis(oxalate)borate and sulfolane for high voltage lithium-ion batteries".ELECTROCHIMICA ACTA 104(2013):134-139.
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