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Superwetting polypropylene aerogel supported form-stable phase change materials with extremely high organics loading and enhanced thermal conductivity
Hong, Haizhi; Pan, Yu; Sun, Hanxue; Zhu, Zhaoqi; Ma, Chonghua; Wang, Bing; Liang, Weidong; Yang, Baoping; Li, An
刊名SOLAR ENERGY MATERIALS AND SOLAR CELLS
2018-01
卷号174页码:307-313
关键词Polypropylene Aerogel Form-stable Phase change material Thermal conductivity
ISSN号0927-0248
DOI10.1016/j.solmat.2017.09.026
英文摘要The development of high efficient materials or devices for storage and utilization of sustainable thermal energy should be of great importance in alleviating energy crisis. Herein, we reported the fabrication of superwetting polypropylene (PP) aerogel as the support materials for construction of form-stable phase change materials (PCMs) composites. Due to its abundant porosity, light weight of aerogel in nature, inherent superhydrophobic and superoleophilic properties, lipophilic organic PCMs can be loaded into PP aerogel (PP/PCM) with a high PCMs loading of up to 1060 wt%, which is nearly two orders of magnitudes higher than those mostly reported form-stable PCMs systems. The PP/PCM composites show high latent heat in the range of 141.1 kJ kg(-1) to 159.5 kJ kg(-1) and excellent thermal stability and recyclability where their latent heat nearly remains unchanged even after 50 times of melting/freezing cycles. Results obtained from the X-ray diffraction (XRD) show that the incorporation of organic PCMs into PP aerogel network decreases the crystal size of PCMs in the composites. More interestingly, the PP/PCM composites show an enhanced thermal conductivity, in the case of PP/Paraffin composite, which is over two times of that of paraffin. Having the advantages of low cost and abundant resource of PP, simple preparatory process, high PCMs loading, good stability, recyclability and thermal conductivity, this the PP/PCM composites may have great potential for renewable energy saving applications.
资助项目National Natural Science Foundation of China[51403092][51462021][51663012][41361070] ; Natural Science Foundation of Gansu Province, China[1610RJYA001] ; Support Program for Hongliu Young Teachers[Q201411] ; Hongliu Elitist Scholars of LUT[J201401] ; State Ethnic Affairs Commission[[2016]57]
WOS研究方向Energy & Fuels ; Materials Science ; Physics
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000415392500037
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/32860]  
专题石油化工学院
图书馆
通讯作者Li, An
作者单位Lanzhou Univ Technol, Coll Petrochem Technol, Langongping Rd 287, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Hong, Haizhi,Pan, Yu,Sun, Hanxue,et al. Superwetting polypropylene aerogel supported form-stable phase change materials with extremely high organics loading and enhanced thermal conductivity[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS,2018,174:307-313.
APA Hong, Haizhi.,Pan, Yu.,Sun, Hanxue.,Zhu, Zhaoqi.,Ma, Chonghua.,...&Li, An.(2018).Superwetting polypropylene aerogel supported form-stable phase change materials with extremely high organics loading and enhanced thermal conductivity.SOLAR ENERGY MATERIALS AND SOLAR CELLS,174,307-313.
MLA Hong, Haizhi,et al."Superwetting polypropylene aerogel supported form-stable phase change materials with extremely high organics loading and enhanced thermal conductivity".SOLAR ENERGY MATERIALS AND SOLAR CELLS 174(2018):307-313.
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