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Synthesis and self-assembly of chalcone-based organogels
Zhang, Ying-Peng; Wang, Bao-Xu; Yang, Yun-Shang; Liang, Chuan; Yang, Chen; Hong-Li Chai
刊名COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
2019-09-20
卷号577页码:449-455
关键词Naphthalene Chalcone Organogels Alkyl chains Self-assembly
ISSN号0927-7757
DOI10.1016/j.colsurfa.2019.06.010
英文摘要Five naphthalene-type chalcone organogelators with different hydrophobic alkyl units, were designed and synthesized. The prepared organogelators demonstrated excellent gel properties in some selected solvents, such as cyclohexane, tert-Butanol, isooctane, and isopropanol etc. The results for thermal stability showed that the alkyl chain length attached to the chalcone also had an important influence on the gelation behavior. Under identical concentrations increasing the length of alkyl chains of the gel molecules and then the gel-to-sol transition temperature value is increased too. It has found that the hydrogen bonding between molecules, the van der Waals force and the pi-pi stacking provide multiple driving forces for gel self-assembly using various techniques. The morphology of the xerogel was investigated by Scanning Electron Microscope (SEM). As the length of the carbon chain increases, the dry gel tends to form a lamellar network structure. The UV-vis absorption and emission spectra of the gel molecules were also studied.
WOS研究方向Chemistry
语种英语
出版者ELSEVIER
WOS记录号WOS:000477008000051
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/31563]  
专题石油化工学院
通讯作者Zhang, Ying-Peng; Yang, Yun-Shang
作者单位Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Ying-Peng,Wang, Bao-Xu,Yang, Yun-Shang,et al. Synthesis and self-assembly of chalcone-based organogels[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2019,577:449-455.
APA Zhang, Ying-Peng,Wang, Bao-Xu,Yang, Yun-Shang,Liang, Chuan,Yang, Chen,&Hong-Li Chai.(2019).Synthesis and self-assembly of chalcone-based organogels.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,577,449-455.
MLA Zhang, Ying-Peng,et al."Synthesis and self-assembly of chalcone-based organogels".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 577(2019):449-455.
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