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Electro-catalytic degradation properties of Ti/SnO2–Sb electrodes doped with different rare earths
Zhu, Fu-Liang1,2; Meng, Yan-Shuang1,2; Huang, Xiu-Yang2
刊名Rare Metals
2016-05-01
卷号35期号:5页码:412-418
关键词Decomposition Organic pollutants Protective coatings Rare earths Scanning electron microscopy Thermolysis Titanium oxides Catalytic degradation Galvanostatic control Large-scale applications Linear sweep voltammetry Oxygen evolution Rare earth doped Surface coatings Thermal decomposition methods
ISSN号10010521
DOI10.1007/s12598-014-0397-x
英文摘要Ti/SnO2–Sb electrode has a good effect on the removal of organic pollutants. But its short service life limits its large-scale application in industry. Electro-catalytic degradation performances and service life of the electrode can be significantly improved by doping rare earth (RE) ions into the oxide coating of Ti/SnO2–Sb electrode. Ti/SnO2–Sb electrodes doped with different RE elements (Ce, Dy, La, and Eu) were prepared by the thermal decomposition method at 550 °C. Electro-catalytic degradation performances of electrodes doped with different RE elements were evaluated by linear sweep voltammetry (LSV) and Tafel curves. During the electrolysis, the conversion of p-nitrophenol was performed with these electrodes as anodes under galvanostatic control. The structures and morphologies of the surface coating of the electrodes were characterized by scanning electron microscope (SEM). The results demonstrate that the electro-catalytic degradation performances of Ti/SnO2–Sb electrodes are improved to different levels by doping different RE ions. Improved Ti/SnO2–Sb electrodes by the introduction of different RE have higher oxygen evolution potential, better electro-catalysis ability, better coverage, and longer electrode life. © 2014, The Nonferrous Metals Society of China and Springer-Verlag Berlin Heidelberg.
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
出版者University of Science and Technology Beijing
WOS记录号WOS:000374572800010
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/112492]  
专题材料科学与工程学院
省部共建有色金属先进加工与再利用国家重点实验室
作者单位1.State Key Laboratory of Gansu Advanced Nonferrous Metal Materials, Lanzhou University of Technology, Lanzhou; 730050, China;
2.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China
推荐引用方式
GB/T 7714
Zhu, Fu-Liang,Meng, Yan-Shuang,Huang, Xiu-Yang. Electro-catalytic degradation properties of Ti/SnO2–Sb electrodes doped with different rare earths[J]. Rare Metals,2016,35(5):412-418.
APA Zhu, Fu-Liang,Meng, Yan-Shuang,&Huang, Xiu-Yang.(2016).Electro-catalytic degradation properties of Ti/SnO2–Sb electrodes doped with different rare earths.Rare Metals,35(5),412-418.
MLA Zhu, Fu-Liang,et al."Electro-catalytic degradation properties of Ti/SnO2–Sb electrodes doped with different rare earths".Rare Metals 35.5(2016):412-418.
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