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Optical Properties of Cu2+ Doped ZnAl2O4 Nanoparticles
Huang, Shang-Pan1,2; Wei, Zhi-Qiang1,2; Wu, Xiao-Juan1,2; Chen, Xiu-Juan1,3; Yuan, Li-Hua2
刊名Faguang Xuebao/Chinese Journal of Luminescence
2019-11-01
卷号40期号:11页码:1386-1393
关键词Aluminum compounds Band structure Binding energy Crystal structure Heat treatment High resolution transmission electron microscopy Nanoparticles Optical emission spectroscopy Optical properties Photoelectron spectroscopy Semiconductor quantum wells Synthesis (chemical) Ultraviolet visible spectroscopy X ray photoelectron spectroscopy Zinc compounds Element distribution Field-emission transmission electron microscopies First principle calculations Hydrothermal methods Infrared spectrum Luminescence quenching Treatment technologies UV-vis spectroscopy
ISSN号10007032
DOI10.3788/fgxb20194011.1386
英文摘要Zn1-xCuxAl2O4 (x=0, 0.05, 0.10, 0.15, 0.20) nanoparticles with different doping ratios were synthesized by hydrothermal method and heat treatment technology. The crystal structure, morphology, element distribution, binding energy and optical property of the samples were characterized by X-ray diffraction(XRD), field emission transmission electron microscopy(FETEM), Fourier infrared spectrum(FT-IR), X-ray photoelectron spectroscopy(XPS), photoluminescence(PL) and UV-Vis spectroscopy(UV-Vis), and the energy band structure of various defects in ZnAl2O4 structure was calculated by means of the first-principle calculations. The experimental results show that Zn1-xCuxAl2O4 nanoparticles prepared by this method possess spinel structure. The XPS spectra demonstrate that the doped Cu2+ all occupy the tetrahedral sites for Zn0.9Cu0.10Al2O4 samples, the PL spectra show luminescence quenching occurs for Cu2+ doped samples, the UV-Vis result shows the new absorption peak appeared after Cu2+ doped, and the optical properties of the sample are explained by the first principle calculations. © 2019, Science Press. All right reserved.
语种中文
出版者Editorial Office of Chinese Optics
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/150491]  
专题外国语学院
兰州理工大学
机电工程学院
作者单位1.State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou; 730050, China;
2.School of Science, Lanzhou University of Technology, Lanzhou; 730050, China;
3.School of Mechanical and Electrical Engineering, Lanzhou University of Technology, Lanzhou; 730050, China
推荐引用方式
GB/T 7714
Huang, Shang-Pan,Wei, Zhi-Qiang,Wu, Xiao-Juan,et al. Optical Properties of Cu2+ Doped ZnAl2O4 Nanoparticles[J]. Faguang Xuebao/Chinese Journal of Luminescence,2019,40(11):1386-1393.
APA Huang, Shang-Pan,Wei, Zhi-Qiang,Wu, Xiao-Juan,Chen, Xiu-Juan,&Yuan, Li-Hua.(2019).Optical Properties of Cu2+ Doped ZnAl2O4 Nanoparticles.Faguang Xuebao/Chinese Journal of Luminescence,40(11),1386-1393.
MLA Huang, Shang-Pan,et al."Optical Properties of Cu2+ Doped ZnAl2O4 Nanoparticles".Faguang Xuebao/Chinese Journal of Luminescence 40.11(2019):1386-1393.
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