Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br
	Chen Zhaohui; Pan Shilie; Dong Xiaoyu; Yang Zhihua; Zhang Min; Su Xin
刊名	INORGANICA CHIMICA ACTA
	2013
卷号	406 期号:9 页码:205-210
关键词	Na3B6O10Br Synthesis Crystal and electronic structures Borate
ISSN号	0020-1693
通讯作者	Pan, SL
中文摘要	A new bromoborate Na3B6O10Br has been synthesized by the high temperature solution method. It crystallizes in orthorhombic space group Pnma (No. 53) with lattice constants a = 12.780(8) angstrom, b = 9.914(6) angstrom, c = 7.518(2) angstrom, Z = 4. The crystal structure contains an infinite three-dimensional matrix that is built from B6O13 units, Na(1)O4Br2, Na(2)O6Br, and Na(3)O-6 polyhedra. Interestingly, four B6O13 units are interconnected by oxygen atoms forming hexadecagon huge pores. IR spectrum, UV-Vis-NIR diffuse reflectance spectrum, and thermogravimetric analyses for the compound are also presented, as are band structures and density of states calculations. (C) 2013 Elsevier B. V. All rights reserved.
学科主题	Chemistry
收录类别	SCI
资助信息	973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51202210, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; CAS; Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2639]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Univ, Phys & Chem Testing Ctr, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chen Zhaohui,Pan Shilie,Dong Xiaoyu,et al. Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br[J]. INORGANICA CHIMICA ACTA,2013,406(9):205-210.
APA	Chen Zhaohui,Pan Shilie,Dong Xiaoyu,Yang Zhihua,Zhang Min,&Su Xin.(2013).Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br.INORGANICA CHIMICA ACTA,406(9),205-210.
MLA	Chen Zhaohui,et al."Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br".INORGANICA CHIMICA ACTA 406.9(2013):205-210.