Pb8M(BO3)(6) (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Pb8M(BO3)(6) (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure
	Huang Zhenjun; Pan Shilie; Yang Zhihua; Yu Hongwei; Dong Xiaoyu; Zhao Wenwu; Dong Lingyun; Su Xiri
刊名	SOLID STATE SCIENCES
	2013
卷号	15 期号:1 页码:73-78
关键词	Pb8Zn(BO3)(6) Pb8Cd(BO3)(6) Borate Synthesis Crystal structure
ISSN号	1293-2558
通讯作者	Pan, SL
中文摘要	Single crystals of Pb8M(BO3)(6) (M=Zn, Cd) have been successfully synthesized by high temperature solution method and their structures are determined by single-crystal X-ray diffraction methods. The compounds crystallize in the trigonal space group R (3) over bar (No.148) with unit:cell parameters a = 9.505(6) angstrom, c = 18.162(9) angstrom, V = 1421(2) angstrom(3) for the Zn compound and a = 9.5584(16) angstrom, c = 18.670(3) angstrom, V = 1477.2(6) angstrom(3) for the Cd compound. Both of the materials represent a new two-dimensional (2D) (infinity)[Pb8B6O18](2-) layer, which is composed of BO3 and PbOx (x = 4,6) polyhedra. The layers are further bridged by the M2+ (Zn2+, Cd2+) ions, giving rise to a three-dimensional (3D) framework. Thermal analysis, IR spectroscopy, UV-Vis-NIR diffuse reflectance spectra, and band structure calculations are performed on the reported compounds.
学科主题	Chemistry ; Physics
收录类别	SCI
资助信息	National Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; Xinjiang Uygur Autonomous Region of China 201130111, 201116143
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2728]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Huang Zhenjun,Pan Shilie,Yang Zhihua,et al. Pb8M(BO3)(6) (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure[J]. SOLID STATE SCIENCES,2013,15(1):73-78.
APA	Huang Zhenjun.,Pan Shilie.,Yang Zhihua.,Yu Hongwei.,Dong Xiaoyu.,...&Su Xiri.(2013).Pb8M(BO3)(6) (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure.SOLID STATE SCIENCES,15(1),73-78.
MLA	Huang Zhenjun,et al."Pb8M(BO3)(6) (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure".SOLID STATE SCIENCES 15.1(2013):73-78.