Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties

doi:10.1039/d1cy02112e

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	Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties
	Li, Zhenyu 1,4; Zhao, Linmin 2; Chen, Hui 1; Liang, Xiao 1; Ai, Xuan 1; Xie, Zhoubing 1; Li, Xiaotian 4; Yang, Feng 3; Liu, Hongyang 2; Zou, Xiaoxin 1
刊名	CATALYSIS SCIENCE & TECHNOLOGY
	2021-12-13
页码	5
ISSN号	2044-4753
DOI	10.1039/d1cy02112e
通讯作者	Liu, Hongyang(liuhy@imr.ac.cn) ; Zou, Xiaoxin(xxzou@jlu.edu.cn)
英文摘要	Three crystal phases of Pd-B intermetallics, namely, Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reactions are studied. In both reactions, their catalytic activities are found to increase in the order Pd, Pd6B, Pd5B2 and Pd2B. This activity trend is strongly associated with the Pd(d)-B(s,p) orbital hybridization-regulated surface adsorption properties.
资助项目	National Natural Science Foundation of China (NSFC)[21922507] ; National Natural Science Foundation of China (NSFC)[21771079] ; National Natural Science Foundation of China (NSFC)[21901083] ; National Natural Science Foundation of China (NSFC)[22179046] ; Fok Ying Tung Education Foundation[161011] ; Fundamental Research Funds for the Central Universities, NSFC[21621001] ; 111 Project[B17020]
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000747885300001
资助机构	National Natural Science Foundation of China (NSFC) ; Fok Ying Tung Education Foundation ; Fundamental Research Funds for the Central Universities, NSFC ; 111 Project
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/173617]
专题	金属研究所_中国科学院金属研究所
通讯作者	Liu, Hongyang; Zou, Xiaoxin
作者单位	1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 4.Jilin Univ, Coll Mat Sci & Engn, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Li, Zhenyu,Zhao, Linmin,Chen, Hui,et al. Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties[J]. CATALYSIS SCIENCE & TECHNOLOGY,2021:5.
APA	Li, Zhenyu.,Zhao, Linmin.,Chen, Hui.,Liang, Xiao.,Ai, Xuan.,...&Zou, Xiaoxin.(2021).Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties.CATALYSIS SCIENCE & TECHNOLOGY,5.
MLA	Li, Zhenyu,et al."Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties".CATALYSIS SCIENCE & TECHNOLOGY (2021):5.