Multi-peaked broad-band red phosphor Y3Si6N11:Pr3+ for white LEDs and temperature sensing | |
D. S. Sun,L. L. Zhang,Z. D. Hao,H. Wu,H. J. Wu,Y. S. Luo,L. Yang,X. Zhang,F. Liu and J. H. Zhang | |
刊名 | Dalton Transactions |
2020 | |
卷号 | 49期号:48页码:17779-17785 |
ISSN号 | 1477-9226 |
DOI | 10.1039/d0dt03532g |
英文摘要 | The indispensable broad-band red phosphors for LED lighting generally show a long emission tail for wavelengths longer than 650 nm, which consumes excitation energy but contributes little luminance. Here, we report, for the first time, a broad red emission band with a steep falling edge at 652 nm, formed of widely distributed D-1(2) -> H-3(4) emission lines of Pr3+ in Y3Si6N11 due to a large Stark splitting of the H-3(4) (930 cm(-1)) and D-1(2) (725 cm(-1)) levels. The red emission exhibits a 43 nm bandwidth, which is the widest in Pr3+-doped phosphors reported so far. The red Y3Si6N11:Pr3+ phosphor was applied for the fabrication of 310 nm UV chip-based white LEDs, and a high color rendering index of 96 at a low correlated color temperature of 4188 K was achieved. Furthermore, a temperature-sensing scheme was proposed based on the temperature-dependent intensity ratios of the emission lines from the thermally coupled and large Stark splitting levels of the D-1(2) state. Relative sensitivities as a function of temperature were studied in the range of 93-473 K. The findings of this study indicate that Y3Si6N11:Pr3+ is an attractive broad-band red phosphor for both high color rendering white LEDs and temperature sensing applications. |
URL标识 | 查看原文 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciomp.ac.cn/handle/181722/64708] |
专题 | 中国科学院长春光学精密机械与物理研究所 |
推荐引用方式 GB/T 7714 | D. S. Sun,L. L. Zhang,Z. D. Hao,H. Wu,H. J. Wu,Y. S. Luo,L. Yang,X. Zhang,F. Liu and J. H. Zhang. Multi-peaked broad-band red phosphor Y3Si6N11:Pr3+ for white LEDs and temperature sensing[J]. Dalton Transactions,2020,49(48):17779-17785. |
APA | D. S. Sun,L. L. Zhang,Z. D. Hao,H. Wu,H. J. Wu,Y. S. Luo,L. Yang,X. Zhang,F. Liu and J. H. Zhang.(2020).Multi-peaked broad-band red phosphor Y3Si6N11:Pr3+ for white LEDs and temperature sensing.Dalton Transactions,49(48),17779-17785. |
MLA | D. S. Sun,L. L. Zhang,Z. D. Hao,H. Wu,H. J. Wu,Y. S. Luo,L. Yang,X. Zhang,F. Liu and J. H. Zhang."Multi-peaked broad-band red phosphor Y3Si6N11:Pr3+ for white LEDs and temperature sensing".Dalton Transactions 49.48(2020):17779-17785. |
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