Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination

	Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination
	Xu N(许诺); Xu JN(徐佳能); Zhu Q(朱庆); Liu C(刘超)
刊名	Advanced Synthesis & Catalysis
	2020-12
期号	363 页码:2403-2407
关键词	Boron Allylic Compounds Vinylboronates Zweifel Olefination
英文摘要	A method for the synthesis of allylboronates via Zweifel-type deprotonative olefination was demonstrated. Tetrasubstituted vinylboronates were used as the substrates. NCS (N-chlorosuccinimide) was used as a bifunctional additive, electrophile and base. This method exhibited a different elimination strategy in Zweifel type transformation to afford allylboronates. The homo-alcohols and alkenes were stereoselective synthesized from the obtained allylboronates, demonstrating the synthetic value of this methodology.
内容类型	期刊论文
源URL	[http://ir.licp.cn/handle/362003/27485]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xu N(许诺)
推荐引用方式 GB/T 7714	Xu N,Xu JN,Zhu Q,et al. Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination[J]. Advanced Synthesis & Catalysis,2020(363):2403-2407.
APA	许诺,徐佳能,朱庆,&刘超.(2020).Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination.Advanced Synthesis & Catalysis(363),2403-2407.
MLA	许诺,et al."Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination".Advanced Synthesis & Catalysis .363(2020):2403-2407.