Ionic liquids for CO2 electrochemical reduction

doi:10.1016/j.cjche.2020.10.029

	Ionic liquids for CO2 electrochemical reduction
	Li, Fangfang 2; Mocci, Francesca 3; Zhang, Xiangping 4; Ji, Xiaoyan 2; Laaksonen, Aatto 1,2,5,6
刊名	CHINESE JOURNAL OF CHEMICAL ENGINEERING
	2021-03-01
卷号	31 页码:75-93
关键词	Carbon dioxide Ionic liquids Electro-reduction Electrolyte Electrocatalytic material Computer simulation
ISSN号	1004-9541
DOI	10.1016/j.cjche.2020.10.029
英文摘要	Electrochemical reduction of CO2 is a novel research field towards a CO2-neutral global economy and combating fast accelerating and disastrous climate changes while finding new solutions to store renewable energy in value-added chemicals and fuels. Ionic liquids (ILs), as medium and catalysts (or supporting part of catalysts) have been given wide attention in the electrochemical CO2 reduction reaction (CO2RR) due to their unique advantages in lowering overpotential and improving the product selectivity, as well as their designable and tunable properties. In this review, we have summarized the recent progress of CO2 electro-reduction in IL-based electrolytes to produce higher-value chemicals. We then have highlighted the unique enhancing effect of ILs on CO2RR as templates, precursors, and surface functional moieties of electrocatalytic materials. Finally, computational chemistry tools utilized to understand how the ILs facilitate the CO2RR or to propose the reaction mechanisms, generated intermediates and products have been discussed. (C) 2020 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.
资助项目	Swedish Energy Agency[P47500-1] ; Swedish Research Council[2019-03865] ; Ministry of Research and Innovation of Romania (CNCS -UEFISCDI within PNCDI III)[PN-IIIP4-ID-PCCF-2016-0050] ; Fondazione di Sardegna, Project: "Precious metal-free complexes for catalytic CO2 reduction"[CUP: F71I17000170002]
WOS关键词	EFFICIENT ELECTROCATALYTIC REDUCTION ; VALUE-ADDED CHEMICALS ; CARBON-DIOXIDE ; FORMIC-ACID ; SELECTIVE CONVERSION ; MOLYBDENUM-DISULFIDE ; DENSITY FUNCTIONALS ; HYDROGEN EVOLUTION ; SYNGAS PRODUCTION ; IMIDAZOLIUM IONS
WOS研究方向	Engineering
语种	英语
出版者	CHEMICAL INDUSTRY PRESS CO LTD
WOS记录号	WOS:000651052400010
资助机构	Swedish Energy Agency ; Swedish Research Council ; Ministry of Research and Innovation of Romania (CNCS -UEFISCDI within PNCDI III) ; Fondazione di Sardegna, Project: "Precious metal-free complexes for catalytic CO2 reduction"
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/48938]
专题	中国科学院过程工程研究所
通讯作者	Ji, Xiaoyan; Laaksonen, Aatto
作者单位	1.Petru Poni Inst Macromol Chem, Ctr Adv Res Bionanocojugates & Biopolymers, Iasi 700469, Romania 2.Lulea Univ Technol, Div Energy Sci, Energy Engn, S-97187 Lulea, Sweden 3.Univ Cagliari, Dept Chem & Geol Sci, I-09042 Monserrato, Italy 4.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc,State Key, Beijing 100190, Peoples R China 5.Stockholm Univ, Dept Mat & Environm Chem, Div Phys Chem, Arrhenius Lab, S-10691 Stockholm, Sweden 6.Nanjing Tech Univ, State Key Lab Mat Oriented & Chem Engn, Nanjing 211816, Peoples R China
推荐引用方式 GB/T 7714	Li, Fangfang,Mocci, Francesca,Zhang, Xiangping,et al. Ionic liquids for CO2 electrochemical reduction[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2021,31:75-93.
APA	Li, Fangfang,Mocci, Francesca,Zhang, Xiangping,Ji, Xiaoyan,&Laaksonen, Aatto.(2021).Ionic liquids for CO2 electrochemical reduction.CHINESE JOURNAL OF CHEMICAL ENGINEERING,31,75-93.
MLA	Li, Fangfang,et al."Ionic liquids for CO2 electrochemical reduction".CHINESE JOURNAL OF CHEMICAL ENGINEERING 31(2021):75-93.