Urchin-like NiCo2S4 structures synthesized through a one-step solvothermal process for high-performance supercapacitors | |
Yan Hu1; Jie Zhang1; Di Wang1; Jiangbo Sun1; Li Zhang1; Yanjie Liu1; Shiqiu Gao1; Yanbin Cui1 | |
刊名 | 颗粒学报:英文版 |
2019 | |
卷号 | 000期号:004页码:66 |
关键词 | NiCo2S4 PEG Asymmetric supercapacitor Urchin-like structure High specific capacitance |
ISSN号 | 1674-2001 |
英文摘要 | Nickel cobalt sulfides (MCo2S4) have attracted considerable attention as electrode materials for supercapacitors. Herein, a sea-urchin-like NiCo2S4 material was synthesized through a one-step solvothermal process. Polyethylene glycol (PEG) 200 and thiourea were used as a shape-control age nt and sulfur source for in-s让u sulfuration, respectively. The urchin-like NiC02S4 was characterized by X-ray powder diffraction, scanning electron microscopy, Brunauer-Emmett-Teller surface area, and electrochemical measurements. The resulting NiCo2S4 with ion diffusion-favored structure demonstrated remarkable electrochemical characteristics for supercapacitor with a high specific capacitance (1334F/g at 0.5 A/g) and superior rate capability (78.1% of the original capacity from 0.5 to 20 A/g) in 6M KOH aqueous solution. Furthermore, an asymmetric supercapacitor was assembled using NiCo2S4 as a positive electrode and activated carb on (AC) as a n egative electrode. A NiCo2Sj/AC device exhibited a high energy density of 37.32 Wh/kg at a power density of 317.8 W/kg with capacity retention of 91.9% and up to 2000 charge/discharge cycles at 3 A/g. The results demonstrate that the sea-urchin-like NiCo2S4 has potential applications in supercapacitors. |
资助项目 | [Fund of State Key Laboratory of Multiphase Complex Systems] ; [Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences] |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/44612] |
专题 | 中国科学院过程工程研究所 |
作者单位 | 1.中国科学院过程工程研究所 2.中国科学院大学 |
推荐引用方式 GB/T 7714 | Yan Hu,Jie Zhang,Di Wang,et al. Urchin-like NiCo2S4 structures synthesized through a one-step solvothermal process for high-performance supercapacitors[J]. 颗粒学报:英文版,2019,000(004):66. |
APA | Yan Hu.,Jie Zhang.,Di Wang.,Jiangbo Sun.,Li Zhang.,...&Yanbin Cui.(2019).Urchin-like NiCo2S4 structures synthesized through a one-step solvothermal process for high-performance supercapacitors.颗粒学报:英文版,000(004),66. |
MLA | Yan Hu,et al."Urchin-like NiCo2S4 structures synthesized through a one-step solvothermal process for high-performance supercapacitors".颗粒学报:英文版 000.004(2019):66. |
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