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Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries
Zhao, Jilu1,2; Yang, Mei2; Yang, Nailiang1,2; Wang, Jiangyan1,2; Wang, Dan1,2
刊名CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
2020-05-14
页码7
关键词Hollow Micro- nanostructure Lithium-sulfur battery
ISSN号1005-9040
DOI10.1007/s40242-020-0115-2
英文摘要High-energy-density lithium-sulfur(Li-S) batteries are drawing dramatic research interests to fulfill the ever-increasing demands of electrical vehicles. However, challenges with the insulating property of sulfur and its lithiation products and its large volume expansion, and the shuttle effect of lithium polysulfides, hinder the commercial application of Li-S batteries. Lots of material design concepts have been developed to address the failure modes. Among them, hollow micro-/nanostructures with abundant compositional and geometrical feasibility have been proved fruitful in addressing the current obstacles of Li-S batteries. Here, typical examples of designing hollow micro-/nanostructures to address the problems of Li-S batteries and simultaneously improve the practical capacity and lifespan are highlighted. In particular, the great effect of structural engineering on minimizing volume change, inhibiting the shuttle effect and catalyzing polysulfide conversion are discussed systematically. Finally, future directions of hollow nanostructure design to enhance the progress of Li-S batteries are also provided.
资助项目National Natural Science Foundation of China[21820102002] ; National Natural Science Foundation of China[21590795] ; National Natural Science Foundation of China[51661165013] ; Scientific Instrument Developing Project of the Chinese Academy of Sciences
WOS关键词LI-S BATTERIES ; CARBON NANOSPHERES ; POLYSULFIDE MEDIATOR ; PERFORMANCE ; MICROSPHERES ; NITROGEN ; CATHODE ; NANOTUBES ; NANOCAGES ; CAPACITY
WOS研究方向Chemistry
语种英语
出版者HIGHER EDUCATION PRESS
WOS记录号WOS:000532891300001
资助机构National Natural Science Foundation of China ; Scientific Instrument Developing Project of the Chinese Academy of Sciences
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/40557]  
专题中国科学院过程工程研究所
通讯作者Wang, Jiangyan; Wang, Dan
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Jilu,Yang, Mei,Yang, Nailiang,et al. Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2020:7.
APA Zhao, Jilu,Yang, Mei,Yang, Nailiang,Wang, Jiangyan,&Wang, Dan.(2020).Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,7.
MLA Zhao, Jilu,et al."Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES (2020):7.
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