Preparation of layered double hydroxide intercalated by Gallic acid for boron adsorption
Cai, Liang; Zhang, Yuze; Peng, Xiaowu; Guo, Fan; Ji, Lianmin; Li, Lijuan
刊名JOURNAL OF WATER PROCESS ENGINEERING
2021-12
卷号44
ISSN号2214-7144
DOI10.1016/j.jwpe.2021.102394
英文摘要Recently, water pollution has become very serious especially with trace amounts of boron in solution. In this work, Layered double hydroxide intercalated by Gallic acid (GA-LDH), a prospective candidate material for borate acid adsorption, was synthesized for the first time by direct precipitation method using Gallic acid (GA), magnesium nitrate, and aluminum nitrate as raw materials. The effects of pH, reaction time, initial concentration of boric acid, coexisting ions and other factors on the adsorption capacity of GA-LDH for B were analyzed. The GA-LDH adsorption capacity of 10 mg.g(-1) was reached via the optimized synthesis conditions. And most importantly, compared to conventional NO3-LDH, the adsorption of GA-LDH on B is less disturbed by other ions. The study on the adsorption mechanism revealed that GA-LDH adsorbed boron by complex reaction between the hydroxyls of GA and B(OH)(3) or B(OH)(4)(-) in solution. Adsorption kinetics thermodynamics and indicated the relationship between the equilibrium concentration of B in the solution and the B adsorption capacity at various temperatures followed the Langmuir model and the reaction rate of B was mainly controlled by the chemisorption mechanism. The elution efficiency could reach 75% by using nitric acid as an eluent.
内容类型期刊论文
源URL[http://ir.isl.ac.cn/handle/363002/34191]  
专题青海盐湖研究所_盐湖资源综合利用工程技术中心
推荐引用方式
GB/T 7714
Cai, Liang,Zhang, Yuze,Peng, Xiaowu,et al. Preparation of layered double hydroxide intercalated by Gallic acid for boron adsorption[J]. JOURNAL OF WATER PROCESS ENGINEERING,2021,44.
APA Cai, Liang,Zhang, Yuze,Peng, Xiaowu,Guo, Fan,Ji, Lianmin,&Li, Lijuan.(2021).Preparation of layered double hydroxide intercalated by Gallic acid for boron adsorption.JOURNAL OF WATER PROCESS ENGINEERING,44.
MLA Cai, Liang,et al."Preparation of layered double hydroxide intercalated by Gallic acid for boron adsorption".JOURNAL OF WATER PROCESS ENGINEERING 44(2021).
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