A binary carbon@silica@carbon hydrophobic nanoreactor for highly efficient selective oxidation of aromatic alkanes

doi:10.1039/d1nr05695f

CORC > 金属研究所 > 中国科学院金属研究所

	A binary carbon@silica@carbon hydrophobic nanoreactor for highly efficient selective oxidation of aromatic alkanes
	Xiang, Ganghua 1; Zhang, Lushuang 1; Chen, Junnan 2; Zhang, Bingsen 2; Liu, Zhigang 1
刊名	NANOSCALE
	2021-11-11
卷号	13 期号:43 页码:18140-18147
ISSN号	2040-3364
DOI	10.1039/d1nr05695f
通讯作者	Zhang, Bingsen(bszhang@imr.ac.cn) ; Liu, Zhigang(liuzhigang@hnu.edu.cn)
英文摘要	Nanoreactors with a delimited void space and a large number of mesoporous structures have attracted great attention as potential heterogeneous catalysts. In this work, a cobalt and nitrogen co-doped binary carbon@silica@carbon hydrophobic nanoreactor was synthesized by an in situ synthesis method. Cobalt porphyrin was used as an active component to construct Co-N-x sites, and the purpose of the double carbon layer coating was to enhance the hydrophobicity of the surface of the nanoreactor. The optimal nanoreactor could achieve 96.9% ethylbenzene conversion and 99.1% acetophenone selectivity and showed outstanding universality to many other aromatic alkanes. The superior performance was mainly due to the presence of double carbon layers and the high content of Co-N-x sites. The double hydrophobic carbon layer coating could not only promote the adsorption of organic molecules, but also implant Co-N-x active sites on both the inner and outer surfaces of the nanoreactor. This work proposed a meaningful strategy to obtain a highly efficient nanoreactor for C-H bond oxidation.
资助项目	National Natural Science Foundation of China[22072164] ; National Natural Science Foundation of China[21872045] ; National Natural Science Foundation of China[21975069] ; Key Project of Research and Development Plan of Hunan Province[2019SK2071] ; Natural Science Foundation of Hunan Province[2020JJ4169] ; Liao Ning Revitalization Talents Program[XLYC1807175]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000713404400001
资助机构	National Natural Science Foundation of China ; Key Project of Research and Development Plan of Hunan Province ; Natural Science Foundation of Hunan Province ; Liao Ning Revitalization Talents Program
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/167164]
专题	金属研究所_中国科学院金属研究所
通讯作者	Zhang, Bingsen; Liu, Zhigang
作者单位	1.Hunan Univ, Coll Chem & Chem Engn, Engn Res Ctr Adv Catalysis, Minist Educ, Changsha 410082, Hunan, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Xiang, Ganghua,Zhang, Lushuang,Chen, Junnan,et al. A binary carbon@silica@carbon hydrophobic nanoreactor for highly efficient selective oxidation of aromatic alkanes[J]. NANOSCALE,2021,13(43):18140-18147.
APA	Xiang, Ganghua,Zhang, Lushuang,Chen, Junnan,Zhang, Bingsen,&Liu, Zhigang.(2021).A binary carbon@silica@carbon hydrophobic nanoreactor for highly efficient selective oxidation of aromatic alkanes.NANOSCALE,13(43),18140-18147.
MLA	Xiang, Ganghua,et al."A binary carbon@silica@carbon hydrophobic nanoreactor for highly efficient selective oxidation of aromatic alkanes".NANOSCALE 13.43(2021):18140-18147.