Phase transitions in CaCO3 under hydrous and anhydrous conditions: Implications for the structural transformations of CaCO3 during subduction processes

doi:10.2138/am-2021-7575

CORC > 海洋研究所 > 中国科学院海洋研究所 > 海洋地质与环境重点实验室

	Phase transitions in CaCO3 under hydrous and anhydrous conditions: Implications for the structural transformations of CaCO3 during subduction processes
	Yuan, Xueyin 4; Mayanovic, Robert A.3; Zhang, Guoliang 1,2
刊名	AMERICAN MINERALOGIST
	2021-11-01
卷号	106 期号:11 页码:1780-1788
关键词	Calcite CaCO3-II CaCO3-III/IIIb aragonite phase transition subduction
ISSN号	0003-004X
DOI	10.2138/am-2021-7575
通讯作者	Yuan, Xueyin(xueyinyuan@live.com)
英文摘要	The transport of calcium carbonate (CaCO3) into the Earth's interior through subduction is one of the key processes in the global cycling of carbon. To develop a better understanding of the CaCO3 structural stability during subduction processes, the phase transitions among CaCO3-I (calcite), CaCO3- II,-III/IIIb, and aragonite under pressure-temperature (P-T) conditions up to 2.5 GPa and 600 degrees C, in hydrous and anhydrous environments, were investigated using a hydrothermal diamond-anvil cell. One displacive and two reconstructive processes during the phase transitions among CaCO3 polymorphs were confirmed from the results obtained from in situ observations and Raman spectroscopic measurements. Meanwhile, the effect of Ca-substitutional metal cations (e.g., Mg2+) in CaCO3 and the presence of an aqueous fluid on the phase transition processes have been determined. Specifically, the CaCO3-I <-> -II phase transition is a displacive process, occurring instantly at pressures varying from 1.6 GPa at room temperature to 1.5 GPa at 500 degrees C with the phase equilibrium boundary having a minimum P-Tpoint at similar to 1.4 GPa at 300 degrees C, and is completely reversible upon cooling and decompression. The CaCO3-II -> -III phase transition is a reconstructive process, observed at P-Tconditions from 2.0 GPa at room temperature to 2.5 GPa at 150 degrees C, and is accomplished by solid recrystallization starting from CaCO3-II, transitioning through an intermediate CaCO3-IIIb, and ending at the CaCO3-III structure. The phase transition between CaCO3-I or-II and aragonite, which is also a reconstructive process, was found to occur by progressive solid recrystallization under high P-T hydrous and anhydrous conditions, or alternatively, via dissolution-precipitation under low -P-T hydrous conditions, depending on the presence of aqueous fluids and the heating rate of the system. The substitution for Ca2+ by other metal cations (e.g., Mg2+, Mn2+, Fe2+) in CaCO3 results in a significant increase in the pressures for the displacive and solid recrystallization reconstructive phase transitions, but has no detectable influence on the CaCO3-I/II <-> aragonite transformation via a dissolution-precipitation process under hydrous conditions. Our results show that the presence of Ca-substitutional metal cations in CaCO3 is a key factor controlling the phase stability of CaCO3 under high P-T conditions, and suggest that aragonite should be the predominant phase in the upper mantle in subduction zones where the heating rate is very low and slab dehydration is prevalent.
资助项目	National Natural Science Foundation of China[91858206] ; National Natural Science Foundation of China[41702039]
WOS研究方向	Geochemistry & Geophysics ; Mineralogy
语种	英语
出版者	MINERALOGICAL SOC AMER
WOS记录号	WOS:000715844000009
内容类型	期刊论文
源URL	[http://ir.qdio.ac.cn/handle/337002/177176]
专题	海洋研究所_海洋地质与环境重点实验室海洋研究所_深海极端环境与生命过程研究中心
通讯作者	Yuan, Xueyin
作者单位	1.Chinese Acad Sci, Inst Oceanol, Ctr Deep Sea Res, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Geol & Environm, Qingdao 266071, Peoples R China 3.Missouri State Univ, Dept Phys Astron & Mat Sci, Springfield, MO 65897 USA 4.Chinese Acad Geol Sci, Inst Mineral Resources, MNR Key Lab Metallogny & Mineral Assessment, Beijing 100037, Peoples R China
推荐引用方式 GB/T 7714	Yuan, Xueyin,Mayanovic, Robert A.,Zhang, Guoliang. Phase transitions in CaCO3 under hydrous and anhydrous conditions: Implications for the structural transformations of CaCO3 during subduction processes[J]. AMERICAN MINERALOGIST,2021,106(11):1780-1788.
APA	Yuan, Xueyin,Mayanovic, Robert A.,&Zhang, Guoliang.(2021).Phase transitions in CaCO3 under hydrous and anhydrous conditions: Implications for the structural transformations of CaCO3 during subduction processes.AMERICAN MINERALOGIST,106(11),1780-1788.
MLA	Yuan, Xueyin,et al."Phase transitions in CaCO3 under hydrous and anhydrous conditions: Implications for the structural transformations of CaCO3 during subduction processes".AMERICAN MINERALOGIST 106.11(2021):1780-1788.