Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties

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	Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties
	Zhao HH(赵华华)1,2 ; Song HL(宋焕玲)1 ; Chou LJ(丑凌军)1 ; Chou LJ(丑凌军)
刊名	Inorganic Chemistry Communications
	2012
卷号	15 页码:261-265
关键词	Wet impregnation strategy Ni@MOF-5 Crotonaldehyde Hydrogenation
ISSN号	1387-7003
通讯作者	丑凌军
英文摘要	Nickel nanoparticles (2–6 nm) were successfully deposited on MOF-5 (Zn₄O(BDC)₃, BDC = 1,4-benzenedicarboxylate) by a facile wet impregnation strategy to prepare Ni@MOF-5 employing Ni(acac)₂ (acac = acetylacetonate) as the precursor in absolute ethanol solvent owing to the sensitivity to the moisture of MOF-5. Ni@MOF-5 exhibited excellent catalytic activity for hydrogenation of C = C bond using crotonaldehyde as a probe molecule under mild reaction conditions (conversion > 90.0%, selectivity > 98.0%, 2.0 MPa, 100 °C, 40 min). In addition, the catalyst could be reused and the structure of MOF-5 framework was still maintained. Therefore, MOF-5 promised a novel candidate of support for hydrogenation catalyst.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China
语种	英语
WOS记录号	WOS:000300812100061
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3889]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Chou LJ(丑凌军)
作者单位	1.Chinese Acad Sci, Stare Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhao HH,Song HL,Chou LJ,et al. Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties[J]. Inorganic Chemistry Communications,2012,15:261-265.
APA	Zhao HH,Song HL,Chou LJ,&丑凌军.(2012).Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties.Inorganic Chemistry Communications,15,261-265.
MLA	Zhao HH,et al."Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties".Inorganic Chemistry Communications 15(2012):261-265.