Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes

doi:10.1002/cctc.202100410

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	Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes
	Cao, Tianlong 1,2; Dai, Xueya 2; Li, Fan 2; Liu, Weijie 2; Bai, Yunli 2; Fu, Yu 1; Qi, Wei 2
刊名	CHEMCATCHEM
	2021-05-11
页码	8
关键词	propane dehydrogenation atomically dispersed cobalt-nitrogen compounds structure-function relationships
ISSN号	1867-3880
DOI	10.1002/cctc.202100410
通讯作者	Fu, Yu(fuyu@mail.neu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn)
英文摘要	A hybrid catalyst comprising atomically dispersed cobalt-nitrogen compounds anchoring on oxidized carbon nanotubes (OCNTs) is prepared and applied in propane dehydrogenation (PDH) reactions. The proposed non-precious catalyst exhibits high initial conversion (similar to 20 %) and excellent selectivity of propene (>95 %), which is superior to those of metal-free nanocarbon and some metal-based catalysts. The chemical composition and structure of the proposed hybrid catalysts are elucidated by a series of characterizations and control experiments with a single component. These characterization results combined with the kinetic analysis indicate that the catalytic activity mainly originates from the cobalt-nitrogen (Co-N) species supported on the OCNT surface. The present work sheds light on the structure-function relationships of CoN catalysts, paving the way to develop non-precious catalysts for PDH reactions.
资助项目	NSFC of China[22072163] ; NSFC of China[21761132010] ; NSFC of China[91645114] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; Natural Science Foundation of Liaoning Province of China[2019-MS-296]
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000649249100001
资助机构	NSFC of China ; Natural Science Foundation of Liaoning Province of China
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/161617]
专题	金属研究所_中国科学院金属研究所
通讯作者	Fu, Yu; Qi, Wei
作者单位	1.Northeastern Univ, Dept Chem, Coll Sci, 3-11 Wenhua Rd, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Cao, Tianlong,Dai, Xueya,Li, Fan,et al. Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes[J]. CHEMCATCHEM,2021:8.
APA	Cao, Tianlong.,Dai, Xueya.,Li, Fan.,Liu, Weijie.,Bai, Yunli.,...&Qi, Wei.(2021).Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes.CHEMCATCHEM,8.
MLA	Cao, Tianlong,et al."Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes".CHEMCATCHEM (2021):8.