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Under-Deposit Corrosion of Carbon Steel Beneath Full Coverage of CaCO3 Deposit Layer under Different Atmospheres
Pang, Lin2,3; Wang, Zhengbin2; Emori, Wilfred1; Zheng, Yugui2
刊名JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
2021-06-01
页码12
关键词CaCO3 deposit layer carbon dioxide carbon steel dissolved oxygen wire beam electrode under-deposit corrosion
ISSN号1059-9495
DOI10.1007/s11665-021-05926-7
通讯作者Wang, Zhengbin(zbwang12s@imr.ac.cn)
英文摘要The under-deposit corrosion of carbon steel beneath the full coverage of CaCO3 deposit layer in 3.5 wt.% NaCl solution under different atmospheres has been investigated by electrochemical tests, wire beam electrode technique and morphology characterization. The results indicate that dissolved O-2 and CO2 can affect the corrosion of carbon steel under the CaCO3 deposit layer by influencing the cathodic reactions, with the oxygen reduction reaction and reduction reaction of H2CO3 being the dominant cathodic reactions for the systems without and with CO2 injection, respectively. Dissolved O-2 can enhance the localized under-deposit corrosion tendency by forming oxygen concentration cells beneath the deposit layer, while its effect on the general under-deposit corrosion rate depends on the main cathodic reactions. Under atmospheres without CO2 injection, increased concentration of dissolved O-2 can accelerate the general corrosion rate by promoting the oxygen reduction reaction, and it can decrease the general corrosion rate under CO2-purged atmospheres by decreasing the amounts of H2CO3 for the cathodic reaction.
资助项目Natural Science Foundation of Liaoning Province[2019BS249] ; Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province[2017CL18]
WOS研究方向Materials Science
语种英语
出版者SPRINGER
WOS记录号WOS:000656822500003
资助机构Natural Science Foundation of Liaoning Province ; Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/160371]  
专题金属研究所_中国科学院金属研究所
通讯作者Wang, Zhengbin
作者单位1.Sichuan Univ Sci & Engn, Sch Mat Sci & Engn, Zigong 643000, Sichuan, Peoples R China
2.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, 62 Wencui Rd, Shenyang 110016, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, 96 Jinzhai Rd, Hefei 230026, Peoples R China
推荐引用方式
GB/T 7714
Pang, Lin,Wang, Zhengbin,Emori, Wilfred,et al. Under-Deposit Corrosion of Carbon Steel Beneath Full Coverage of CaCO3 Deposit Layer under Different Atmospheres[J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,2021:12.
APA Pang, Lin,Wang, Zhengbin,Emori, Wilfred,&Zheng, Yugui.(2021).Under-Deposit Corrosion of Carbon Steel Beneath Full Coverage of CaCO3 Deposit Layer under Different Atmospheres.JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,12.
MLA Pang, Lin,et al."Under-Deposit Corrosion of Carbon Steel Beneath Full Coverage of CaCO3 Deposit Layer under Different Atmospheres".JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE (2021):12.
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