Methyl Halide to Olefins and Gasoline over Zeolites and SAPO Catalysts: A New Route of MTO and MTG

	Methyl Halide to Olefins and Gasoline over Zeolites and SAPO Catalysts: A New Route of MTO and MTG
	Wei Yingxu 1; Zhang Dazhi 1; Liu Zhongmin 1; Su Bao-Lian 1,2,3
刊名	chinese journal of catalysis
	2012
卷号	33 期号:1 页码:11-21
关键词	methyl halide hydrocarbons zeolite SAPO-34 reaction mechanism
通讯作者	刘中民 ; subaolian
产权排序	1,1
英文摘要	rational and efficient conversion of methane to more useful higher hydrocarbons is one of the most important topics of natural gas utilization. although methane activation and its conversion to valuable compounds attract an increasing attention, methane conversion is often made in indirect way through the very energy-consuming step for syngas production from steam reforming of methane. some promising results appeared to be of significance for the development of an alternative and potential route for the production of high value-added products from methane. efficient conversion of methane to higher hydrocarbons could be realized via methyl halide as the intermediate. after the production of halomethane, they could be transformed to gasoline and light olefins over modified zeolites and sapo molecular sieves. high conversion efficiency and selectivity indicated the feasibility of industrial application. the research gained recently growing interest from the point of view in both fundamental research and industrial application. the study on the reaction mechanism shed light on the possible route of c c bond construction from methyl halide, which is the very important issue of the c-1-reactant conversion to higher hydrocarbons. hydrogen halide generation during methyl halide conversion did not exert apparent impact on the reaction mechanism and the structure stability of the catalysts. this review deals with the evolution of the field and comments the advantages to be explored and the drawbacks to be prevented for the development of new and sustainable methane-to-olefins (mto) and methane-to-gasoline (mtg) routes via methyl halides.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]	chemistry ; engineering
关键词[WOS]	methanol-to-hydrocarbons ; light olefins ; chloromethane transformation ; zsm-5 zeolites ; cao/zeolite composites ; bromine activation ; integrated process ; dimethyl ether ; conversion ; hsapo-34
收录类别	SCI
语种	英语
WOS记录号	WOS:000300474100003
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/118451]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol To Olefins, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Univ Namur FUNDP, Lab Inorgan Mat Chem CMI, B-5000 Namur, Belgium 3.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
推荐引用方式 GB/T 7714	Wei Yingxu,Zhang Dazhi,Liu Zhongmin,et al. Methyl Halide to Olefins and Gasoline over Zeolites and SAPO Catalysts: A New Route of MTO and MTG[J]. chinese journal of catalysis,2012,33(1):11-21.
APA	Wei Yingxu,Zhang Dazhi,Liu Zhongmin,&Su Bao-Lian.(2012).Methyl Halide to Olefins and Gasoline over Zeolites and SAPO Catalysts: A New Route of MTO and MTG.chinese journal of catalysis,33(1),11-21.
MLA	Wei Yingxu,et al."Methyl Halide to Olefins and Gasoline over Zeolites and SAPO Catalysts: A New Route of MTO and MTG".chinese journal of catalysis 33.1(2012):11-21.