Study on Thermodynamic Properties of Ionic Liquid N-Butyl-3-methylpyridinium Bis(trifluoromethylsulfonyl)imide

	Study on Thermodynamic Properties of Ionic Liquid N-Butyl-3-methylpyridinium Bis(trifluoromethylsulfonyl)imide
	Zhang, Qing-Guo 2; Wei, Ying 2; Sun, Si-Si 1,2; Wang, Chang 1; Yang, Miao 1; Liu, Qing-Shan 1; Gao, Yan-An 1
刊名	journal of chemical and engineering data
	2012-08-01
卷号	57 期号:8 页码:2185-2190
通讯作者	刘青山 ; 高艳安
产权排序	2,3
英文摘要	an air- and water-stable hydrophobic ionic liquid n-butyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide ([c(4)3mpy][ntf2]) was synthesized and characterized. density, surface tension, dynamic viscosity, and electrical conductivity of the il were measured and calculated from (278.15 to 353.15) k. the glass transition temperature and decomposition temperature were determined by the differential scanning calorimetry and thermogravimatric analysis. the physicochemical properties like molecular volume, standard molar entropy, lattice energy, parachor, molar enthalpy of vaporization, interstice volume, thermal expansion coefficient, interstice fraction, etc. of the il were estimated by the reported empirical and semiempirical equations. the dynamic viscosity and electrical conductivity data of the il were described by vogel-fulcher-tamman and arrhenius equations, respectively. then, the relationship between the molar conductivity and dynamic viscosity of this il was expressed through the walden rule.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, multidisciplinary ; engineering, chemical
研究领域[WOS]	chemistry ; engineering
关键词[WOS]	temperature molten-salts ; physicochemical properties ; surface-tension ; physical-properties ; thermal-properties ; conductivity ; density ; model ; hexafluorophosphate ; electrolytes
收录类别	SCI
语种	英语
WOS记录号	WOS:000307264200014
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/118386]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China 2.Bohai Univ, Dept Chem, Jinzhou 121000, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Qing-Guo,Wei, Ying,Sun, Si-Si,et al. Study on Thermodynamic Properties of Ionic Liquid N-Butyl-3-methylpyridinium Bis(trifluoromethylsulfonyl)imide[J]. journal of chemical and engineering data,2012,57(8):2185-2190.
APA	Zhang, Qing-Guo.,Wei, Ying.,Sun, Si-Si.,Wang, Chang.,Yang, Miao.,...&Gao, Yan-An.(2012).Study on Thermodynamic Properties of Ionic Liquid N-Butyl-3-methylpyridinium Bis(trifluoromethylsulfonyl)imide.journal of chemical and engineering data,57(8),2185-2190.
MLA	Zhang, Qing-Guo,et al."Study on Thermodynamic Properties of Ionic Liquid N-Butyl-3-methylpyridinium Bis(trifluoromethylsulfonyl)imide".journal of chemical and engineering data 57.8(2012):2185-2190.