Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature

	Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature
	Zhang, Zehui 1,2; Liu, Bing 1,2; Zhao, Zongbao (Kent)3,4
刊名	carbohydrate polymers
	2012-04-15
卷号	88 期号:3 页码:891-895
关键词	Fructose Germanium(IV) chloride Ionic liquids Dehydration 5-Hydroxymethylfurfual
通讯作者	张泽会
产权排序	2,3
英文摘要	conversion of fructose into 5-hydroxymethylfurfural (hmf) catalyzed by germanium(iv) chloride was studied in dimethyl sulfoxide (dmso) and [bmim]cl system at room temperature. the structure of ionic liquids and the ratio of ionic liquids to dmso had a remarkable effect on this new catalytic system. the results indicated that 1-n-butyl-3-methylimidazolium chloride ([bmim]cl) was favorable for the dehydration of fructose to hmf. under optimal conditions, a high hmf yield in 70% was obtained at 25 degrees c. in addition, it was also proved that there was a synergistic effect between the cation and anion of [bmim]cl on the dehydration of fructose to hmf by designed experiments. finally, a possible mechanism for the dehydration of fructose to hmf was proposed. (c) 2012 elsevier ltd. all rights reserved.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, applied ; chemistry, organic ; polymer science
研究领域[WOS]	chemistry ; polymer science
关键词[WOS]	ionic liquids ; imidazolium chloride ; corn stover ; biomass ; dehydration ; cellulose ; salts ; pretreatment
收录类别	SCI
语种	英语
WOS记录号	WOS:000302196200012
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/118217]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.S Cent Univ Nationalities, Coll Chem & Mat Sci, State Ethn Affairs Commiss, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China 2.S Cent Univ Nationalities, Coll Chem & Mat Sci, Minist Educ, Wuhan 430074, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Zehui,Liu, Bing,Zhao, Zongbao . Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature[J]. carbohydrate polymers,2012,88(3):891-895.
APA	Zhang, Zehui,Liu, Bing,&Zhao, Zongbao .(2012).Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature.carbohydrate polymers,88(3),891-895.
MLA	Zhang, Zehui,et al."Conversion of fructose into 5-HMF catalyzed by GeCl4 in DMSO and [Bmim]Cl system at room temperature".carbohydrate polymers 88.3(2012):891-895.