Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide

	Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide
	Zheng, Xi 1,2; Wang, Min 1,2; Sun, Zhiqiang 1; Chen, Chen 1; Ma, Jiping 1; Xu, Jie 1
刊名	catalysis communications
	2012-12-05
卷号	29 页码:149-152
关键词	Bisimidazolium ionic liquids Periodic mesoporous organosilica Copper Cyclohexyl hydroperoxide Decomposition
通讯作者	徐杰
产权排序	1,1
英文摘要	a novel bisimidazolium ionic liquid bridged periodic mesoporous organosilica was prepared. bisimidazolium ionic liquid was incorporated into the framework of mesoporous materials and copper (ii) chloride can be easily introduced to the framework via the formation of cucl42- complex. this copper (ii) ion-containing bisimidazolium ionic liquid bridged material showed high activity and stability in the decomposition of cyclohexyl hydroperoxide. ninety-nine percent conversion and 84% selectivity for cyclohexanone and cyclohexanol (k/a oil) could be obtained. (c) 2012 elsevier b.v. all rights reserved.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	oxidation ; efficient ; water ; deperoxidation ; complexes ; framework ; chlorides ; walls ; pmos
收录类别	SCI
语种	英语
WOS记录号	WOS:000313024300032
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/118065]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Xi,Wang, Min,Sun, Zhiqiang,et al. Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide[J]. catalysis communications,2012,29:149-152.
APA	Zheng, Xi,Wang, Min,Sun, Zhiqiang,Chen, Chen,Ma, Jiping,&Xu, Jie.(2012).Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide.catalysis communications,29,149-152.
MLA	Zheng, Xi,et al."Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide".catalysis communications 29(2012):149-152.