Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts

doi:10.1016/j.jechem.2019.07.007

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts
	Sun, FF ; Yang, RO ; Xia, ZM ; Yang, YQ ; Zhao, Z ; Gu, SQ ; Wu, DS ; Ding, YJ ; Jiang, Z
刊名	JOURNAL OF ENERGY CHEMISTRY
	2020
卷号	42 页码:227-232
关键词	HIGHER ALCOHOLS METHANE AROMATIZATION CARBON-MONOXIDE SELECTIVITY CONVERSION OLEFINS SYNGAS CELLULOSE SODIUM LA2O3
ISSN号	2095-4956
DOI	10.1016/j.jechem.2019.07.007
文献子类	期刊论文
英文摘要	Cobalt carbide (Co2C) was considered as potential catalysts available for large-scale industrialization of transforming syngas (H-2 and CO) to clean fuels. Herein, we successfully synthesized Co-based catalysts with MnO supported, to comprehend the effects of Co2C for Fischer-Tropsch synthesis (FTS) under ambient conditions. The huge variety of product selectivity which was contained by different active sites (Co and Co2C) has been found. Furthermore, density functional theory (DFT) shows that Co2C is efficacious of CO adsorption, whereas is weaker for H adsorption than Co. Combining the advantages of Co and Co2C, the catalyst herein can not only obtain more C5+ products but also suppress methane selectivity. It can be a commendable guide for the design of industrial application products in FTS. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/32829]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Xi An Jiao Tong Univ, Ctr Appl Chem Res, Frontier Inst Sci & Technol, Xian 710049, Shaanxi, Peoples R China 2.Kyoto Univ, Grad Sch Sci, Sakyo Ku, Oiwake Cho, Kyoto, Kyoto 6068502, Japan 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201204, Peoples R China 4.Chinese Acad Sci, Shanghai Adv Res Inst, Zhangjiang Lab, Shanghai Synchrotron Radiat Facil, Shanghai 201210, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100100, Peoples R China 6.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Sun, FF,Yang, RO,Xia, ZM,et al. Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts[J]. JOURNAL OF ENERGY CHEMISTRY,2020,42:227-232.
APA	Sun, FF.,Yang, RO.,Xia, ZM.,Yang, YQ.,Zhao, Z.,...&Jiang, Z.(2020).Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts.JOURNAL OF ENERGY CHEMISTRY,42,227-232.
MLA	Sun, FF,et al."Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts".JOURNAL OF ENERGY CHEMISTRY 42(2020):227-232.