Structure, first-principles calculations and yellow spectral properties of Dy3+: CaLaGa3O7 single crystal | |
Liu, Yunyun1; Pan, Fei2; Tu, Chaoyang3; Gao, Ju1 | |
刊名 | JOURNAL OF LUMINESCENCE |
2021-08-01 | |
卷号 | 236页码:6 |
关键词 | Dy3+:CaLaGa3O7 XRD Rietveld refinement First-principles calculations Spectroscopic characteristics Yellow emission |
ISSN号 | 0022-2313 |
DOI | 10.1016/j.jlumin.2021.118122 |
通讯作者 | Liu, Yunyun(liuyunyun586@163.com) |
英文摘要 | High optical quality Dy3+-doped CaLaGa3O7 (abbreviated as Dy: CLGO below) crystal was grown successfully by the Czochralski technique along the (0 0 1) orientation. The lattice parameters of the as-grown crystal were obtained by Rietveld refinement to its XRD pattern. The electronic structures including band structure and density of state (DOS) were calculated by using first-principles calculations based on density functional theory (DFT). The spectroscopic characteristics of Dy: CLGO are investigated, with special attention to the yellow emission that could be pumped directly by the rapidly developed blue GaN LD. Based on the Judd-Ofelt (J-O) theory, the intensity parameters from the measured line strengths were determined. The J-O parameters were used to predict radiative transition probabilities, radiative lifetime and branching ratios for various excited levels of the Dy: CLGO crystal. The absorption cross-sections of Dy: CLGO at 453 nm are calculated to be 0.14 x 10(-20) cm(2) and 0.11 x 10(-20) cm(2) for pi- and sigma-polarizations, respectively. Meanwhile, Dy: CLGO exhibits strong yellow emission at 574 nm corresponding to the transition F-4(9/2) -> H-6(13/2) with stimulated emission cross-sections of 3.88 x 10(-21) cm(2) and 3.42 x 10(-21) cm(2) for pi- and sigma-polarizations, respectively. The relatively long fluorescence lifetime (565 mu s) indicates a high laser efficiency of the crystal. All results suggest that Dy: CLGO crystal could be a promising candidate for yellow laser at 574 nm pumped by blue GaN LD. |
资助项目 | Shandong Provincial Natural Science Foundation[ZR2020QE034] ; National Key Research and Development Program of China[2016YFB0701002] ; Natural science foundation of shandong province[ZR2017MF005] ; Qingchuang Science and Technology Plan of Shandong Universities[2019KJN001] ; Project Special Funding of Taishan Scholar |
WOS关键词 | SPECTROSCOPIC PROPERTIES ; TRANSITIONS INTENSITIES ; ABSORPTION INTENSITIES ; OPTICAL-TRANSITIONS ; LASER ; EMISSION ; MELILITE ; GROWTH ; ER3+ ; NM |
WOS研究方向 | Optics |
语种 | 英语 |
WOS记录号 | WOS:000663095900007 |
资助机构 | Shandong Provincial Natural Science Foundation ; National Key Research and Development Program of China ; Natural science foundation of shandong province ; Qingchuang Science and Technology Plan of Shandong Universities ; Project Special Funding of Taishan Scholar |
内容类型 | 期刊论文 |
源URL | [http://ir.yic.ac.cn/handle/133337/29436] |
专题 | 烟台海岸带研究所_中科院烟台海岸带研究所知识产出 |
通讯作者 | Liu, Yunyun |
作者单位 | 1.Zaozhuang Univ, Sch Optoelect Engn, Zaozhuang 277160, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China 3.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Yunyun,Pan, Fei,Tu, Chaoyang,et al. Structure, first-principles calculations and yellow spectral properties of Dy3+: CaLaGa3O7 single crystal[J]. JOURNAL OF LUMINESCENCE,2021,236:6. |
APA | Liu, Yunyun,Pan, Fei,Tu, Chaoyang,&Gao, Ju.(2021).Structure, first-principles calculations and yellow spectral properties of Dy3+: CaLaGa3O7 single crystal.JOURNAL OF LUMINESCENCE,236,6. |
MLA | Liu, Yunyun,et al."Structure, first-principles calculations and yellow spectral properties of Dy3+: CaLaGa3O7 single crystal".JOURNAL OF LUMINESCENCE 236(2021):6. |
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