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Carbonation Reaction of Lithium Hydroxide during Low Temperature Thermal Energy Storage Process
Li, Jun2,3,4; Zeng, Tao2,3,4; Kobayashi, Noriyuki1; Wu, Rongjun1; Xu, Haotai1; Deng, Lisheng2,3,4; He, Zhaohong2,3,4; Huang, Hongyu2,3,4
刊名JOURNAL OF RENEWABLE MATERIALS
2021
卷号9期号:9页码:1621-1630
关键词LiOH heat storage low temperature carbonation reaction hydration reaction
ISSN号2164-6325
DOI10.32604/jrm.2021.015231
通讯作者Zeng, Tao(zengtao@ms.giec.ac.cn) ; Huang, Hongyu(huanghy@ms.giec.ac.cn)
英文摘要In order to apply lithium hydroxide (LiOH) as a low temperature chemical heat storage material, the carbonation reaction of LiOH and the prevention method are focused in this research. The carbonation of raw LiOH at storage and hydration condition is experimentally investigated. The results show that the carbonation reaction of LiOH with carbon dioxide (CO2) is confirmed during the hydration reaction. The carbonation of LiOH can be easily carried out with CO2 at room temperature and humidity. LiOH can be carbonated at a humidity range of 10% to 20%, a normal humidity region that air can easily be reached. Furthermore, the carbonation reaction rate has not nearly affected by the increase of reaction temperature. An improved storage method by storing LiOH at a low humidity less than 1.0% can be effectively prevented the carbonation of LiOH. The hydration reaction ratio of LiOH at the improved storage method shows a better result compared to the ordinary storage method. Therefore, the humidity should be carefully controlled during the storage of LiOH before hydration and dehydration reaction when apply LiOH as a low heat chemical storage material.
资助项目Knowledge Hub Aichi, Priority Research Project from Aichi Prefectural Government, Japan, Leading Key Projects of Chinese Academy of Sciences[QYZDYSSW-JSC038] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory, Guangzhou[GML2019ZD0108] ; Science and Technology Planning Project of Guangdong Province, China[2017A050501046]
WOS关键词CHEMICAL HEAT-PUMP ; CACL2 ; HYDRATION ; MIXTURES ; VAPOR ; WATER
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Polymer Science
语种英语
出版者TECH SCIENCE PRESS
WOS记录号WOS:000644278100008
资助机构Knowledge Hub Aichi, Priority Research Project from Aichi Prefectural Government, Japan, Leading Key Projects of Chinese Academy of Sciences ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory, Guangzhou ; Science and Technology Planning Project of Guangdong Province, China
内容类型期刊论文
源URL[http://ir.giec.ac.cn/handle/344007/33030]  
专题中国科学院广州能源研究所
通讯作者Zeng, Tao; Huang, Hongyu
作者单位1.Nagoya Univ, Dept Chem Engn, Nagoya, Aichi 4648603, Japan
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China
4.Southern Marine Sci & Engn Guangdong Lab, Guangzhou 511458, Peoples R China
推荐引用方式
GB/T 7714
Li, Jun,Zeng, Tao,Kobayashi, Noriyuki,et al. Carbonation Reaction of Lithium Hydroxide during Low Temperature Thermal Energy Storage Process[J]. JOURNAL OF RENEWABLE MATERIALS,2021,9(9):1621-1630.
APA Li, Jun.,Zeng, Tao.,Kobayashi, Noriyuki.,Wu, Rongjun.,Xu, Haotai.,...&Huang, Hongyu.(2021).Carbonation Reaction of Lithium Hydroxide during Low Temperature Thermal Energy Storage Process.JOURNAL OF RENEWABLE MATERIALS,9(9),1621-1630.
MLA Li, Jun,et al."Carbonation Reaction of Lithium Hydroxide during Low Temperature Thermal Energy Storage Process".JOURNAL OF RENEWABLE MATERIALS 9.9(2021):1621-1630.
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