In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source

doi:10.1021/acssuschemeng.0c03505

	In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source
	Wang, Chenguang 1,2; Liu, Yong 3; Cui, Zhibing 4; Yu, Xiaohu 5; Zhang, Xinghua 1,2; Li, Yuping 1,2; Zhang, Qi 1,2; Chen, Lungang 1,2; Ma, Longlong 1,2
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2020-08-31
卷号	8 期号:34 页码:12944-12955
关键词	furfural hydrogenation Cu nanoparticles furfuryl alcohol pomelo peel DFT
ISSN号	2168-0485
DOI	10.1021/acssuschemeng.0c03505
通讯作者	Chen, Lungang(chenlg1981@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
英文摘要	A facile approach was developed to directly synthesize carbon-supported metal nanoparticles with pomelo peel as the carbon source and metal nitrate solution as the metal source. Fe/C, Co/C, Ni/C, and Cu/C catalysts were prepared after calcination in N-2 without further reduction. The metal nanoparticles and formation mechanism were investigated by multiple techniques such as XRD, HRTEM, XPS, FTIR spectra, SEM, and TG-MS thermal analysis. In the case of furfural hydrogenation, Cu/C catalyst exhibited the best activity and exclusive selectivity to produce furfuryl alcohol with complete conversion, and excellent selectivity can be maintained at a higher temperature of 240 degrees C. The particle size of Cu nanoparticles can be tuned by the calcination temperature and metal loading for improving catalytic activity. The excellent performance of Cu nanoparticles was also studied by density functional theory calculation, agreeing well with the experiments.
资助项目	National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foundation of China[21878290] ; Natural Science Foundation of Guangdong Province[2017A030313073]
WOS关键词	LIQUID-PHASE HYDROGENATION ; CATALYTIC TRANSFER HYDROGENATION ; BIOMASS ; NI ; CONVERSION ; TRANSFORMATION ; 2-METHYLFURAN ; ACTIVATION ; ROUTES ; METAL
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000567778600023
资助机构	National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/32014]
专题	中国科学院广州能源研究所
通讯作者	Chen, Lungang; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Univ New Hampshire, Dept Chem Engn, Durham, NH 03824 USA 4.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Peoples R China 5.Shaanxi Univ Technol, Sch Chem & Environm Sci, Inst Theoret & Computat Chem, Shaanxi Key Lab Catalysis, Hanzhong 723000, Peoples R China
推荐引用方式 GB/T 7714	Wang, Chenguang,Liu, Yong,Cui, Zhibing,et al. In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(34):12944-12955.
APA	Wang, Chenguang.,Liu, Yong.,Cui, Zhibing.,Yu, Xiaohu.,Zhang, Xinghua.,...&Ma, Longlong.(2020).In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(34),12944-12955.
MLA	Wang, Chenguang,et al."In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.34(2020):12944-12955.