An efficient nanocluster catalyst for Sonogashira reaction

doi:10.1016/j.jcat.2021.07.023

	An efficient nanocluster catalyst for Sonogashira reaction
	Yang, Ying 1,3; Chen, Cheng 1; Xu, Guo-Yong 1; Yuan, Jinyun 2; Ye, Sun-Feng 1; Chen, Li 1; Lv, Qi-Long 1; Luo, Gen 1; Yang, Jinlong 2; Li, Man-Bo 1,3
刊名	JOURNAL OF CATALYSIS
	2021-09-01
卷号	401
关键词	Atomically precise nanoclusters Sonogashira reaction Incorporation Activity and selectivity Recyclability
ISSN号	0021-9517
DOI	10.1016/j.jcat.2021.07.023
通讯作者	Luo, Gen(luogen@ahu.edu.cn) ; Yang, Jinlong(jlyang@ustc.edu.cn) ; Li, Man-Bo(mbli@ahu.edu.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
英文摘要	Pd together with CuI has been well known as the catalyst towards Sonogashira reaction, which provides an effective route to functional alkynes. However, the achievement of high activity and selectivity of this catalytic system is still challenging in some cases. Illustrative examples include their low activity for aryl chloride substrates, and switched selectivity to oxidative coupling products in air atmosphere. In this work, a Cu-incorporated Au-13 nanocluster [Au13Cu2(PPh3)(6)(SC2H4Ph)(6)](+)[NO3](-) (Au13Cu2) was designed and prepared in high yield via rapid synthesis. This atomically precise nanocluster shows the potential to be a novel catalytic system for Sonogashira reaction, featuring high activity and selectivity, as well as good recyclability even in air atmosphere. (C) 2021 Elsevier Inc. All rights reserved.
资助项目	National Natural Science Foundation of China[92061110] ; National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21925303] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; Hefei National Laboratory for Physical Sciences at the Microscale[KF2020102] ; Anhui University[S020118002/113] ; CASHIPS Director's Fund[BJPY2019A02] ; Key Program of the 13th five year plan, CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2020HSC-CIP005]
WOS关键词	ANTI-GALVANIC REDUCTION ; HETEROGENEOUS CATALYSIS ; HOMOGENEOUS CATALYSIS ; AU-25 NANOCLUSTER ; ALKYL BROMIDES ; GOLD ; LIGANDS ; PHENYLACETYLENE ; HYDROGENATION ; COUPLINGS
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
WOS记录号	WOS:000691529200006
资助机构	National Natural Science Foundation of China ; Hefei National Laboratory for Physical Sciences at the Microscale ; Anhui University ; CASHIPS Director's Fund ; Key Program of the 13th five year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/125161]
专题	中国科学院合肥物质科学研究院
通讯作者	Luo, Gen; Yang, Jinlong; Li, Man-Bo; Wu, Zhikun
作者单位	1.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Anhui Key Lab Nanomat & Nanotechnol, CAS Ctr Excellence Nanosci, Key Lab Mat Phys,Inst Solid State Phys,HFIPS, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Yang, Ying,Chen, Cheng,Xu, Guo-Yong,et al. An efficient nanocluster catalyst for Sonogashira reaction[J]. JOURNAL OF CATALYSIS,2021,401.
APA	Yang, Ying.,Chen, Cheng.,Xu, Guo-Yong.,Yuan, Jinyun.,Ye, Sun-Feng.,...&Wu, Zhikun.(2021).An efficient nanocluster catalyst for Sonogashira reaction.JOURNAL OF CATALYSIS,401.
MLA	Yang, Ying,et al."An efficient nanocluster catalyst for Sonogashira reaction".JOURNAL OF CATALYSIS 401(2021).