Constructing Fe-MOF-Derived Z-Scheme Photocatalysts with Enhanced Charge Transport: Nanointerface and Carbon Sheath Synergistic Effect

doi:10.1021/acsami.0c06601

	Constructing Fe-MOF-Derived Z-Scheme Photocatalysts with Enhanced Charge Transport: Nanointerface and Carbon Sheath Synergistic Effect
	Li, Ya 1,3,4; Xia, Yu 5; Liu, Kuiliang 1,3,4; Ye, Kaihang 6; Wang, Qiushi 6; Zhang, Shanqing 2; Huang, Yongchao 1,3,4; Liu, Hong 7
刊名	ACS APPLIED MATERIALS & INTERFACES
	2020-06-03
卷号	12 期号:22 页码:25494-25502
关键词	photocatalysis Z-scheme nanointerface carbon sheath environmental treatment
ISSN号	1944-8244
DOI	10.1021/acsami.0c06601
通讯作者	Zhang, Shanqing(s.zhang@griffith.edu.au) ; Huang, Yongchao(huangych@gzhu.edu.cn)
英文摘要	Creatively constructing Z-scheme composites is a promising and common strategy for designing effective photocatalyst systems. Herein, we synthesized Z-scheme Fe2O3@Ag-ZnOgC heterostructures from the Fe-MOFs and applied it to photodegradation of tetracycline and methylene blue pollutants in wastewater. The optimized sample exhibits a remarkable performance as well as stability under visible light irradiation. The calculating and experimental results demonstrate that the Fe2O3@ ZnO nanointerface and carbon sheath together boost the transfer efficiency of photogenerated carriers and absorption ability, thereby improving the photocatalytic activity. Furthermore, detailed mechanism investigation reveals the pivotal role of reactive oxygen species ((OH)-O-center dot and O-center dot(2)-) generated, resulting in remarkable performance. In addition, cell biology experiments reveal that the wastewater after photocatalytic treatment has good biological compatibility, which is important for applications. This work provides valuable information for constructing high-performance Z-scheme photocatalysts from MOFs for environmental treatment.
资助项目	Natural Science Foundation of China[21706295] ; Natural Science Foundation of China[51525805] ; Natural Science Foundation of Guangdong Province[2020A1515010798] ; Pearl River S&T Nova Program of Guangzhou[201906010024]
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000538515700103
内容类型	期刊论文
源URL	[http://119.78.100.138/handle/2HOD01W0/11204]
专题	中国科学院重庆绿色智能技术研究院
通讯作者	Zhang, Shanqing; Huang, Yongchao
作者单位	1.Guangzhou Univ, Guangzhou Key Lab Clean Energy & Mat, Guangzhou 510006, Peoples R China 2.Griffith Univ, Country Ctr Clean Environm & Energy, Sch Environm & Sci, Southport, Qld 4215, Australia 3.Guangzhou Univ, Inst Environm Res Greater Bay Area, Guangzhou 510006, Peoples R China 4.Guangzhou Univ, Key Lab Water Qual & Conservat Pearl River Delta, Minist Educ, Guangzhou 510006, Peoples R China 5.South China Univ Technol, Dept Gastroenterol & Hepatol, Guangzhou Digest Dis Ctr, Guangzhou Peoples Hosp 1,Sch Med, Guangzhou 510180, Peoples R China 6.Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Guangdong, Peoples R China 7.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 401122, Peoples R China
推荐引用方式 GB/T 7714	Li, Ya,Xia, Yu,Liu, Kuiliang,et al. Constructing Fe-MOF-Derived Z-Scheme Photocatalysts with Enhanced Charge Transport: Nanointerface and Carbon Sheath Synergistic Effect[J]. ACS APPLIED MATERIALS & INTERFACES,2020,12(22):25494-25502.
APA	Li, Ya.,Xia, Yu.,Liu, Kuiliang.,Ye, Kaihang.,Wang, Qiushi.,...&Liu, Hong.(2020).Constructing Fe-MOF-Derived Z-Scheme Photocatalysts with Enhanced Charge Transport: Nanointerface and Carbon Sheath Synergistic Effect.ACS APPLIED MATERIALS & INTERFACES,12(22),25494-25502.
MLA	Li, Ya,et al."Constructing Fe-MOF-Derived Z-Scheme Photocatalysts with Enhanced Charge Transport: Nanointerface and Carbon Sheath Synergistic Effect".ACS APPLIED MATERIALS & INTERFACES 12.22(2020):25494-25502.