Hydroformylation of dicyclopentadiene to monoformyltricyclodecenes over supported ultra-low content Rh catalysts | |
Li, CY (Li, Chengyang)[ 1,2 ]; Li, HY (Li, Hongyi)[ 3 ]; Zhang, LB (Zhang, Libo)[ 1,2 ]; Ma, YB (Ma, Yubo)[ 1 ]; Wang, TF (Wang, Tianfu)[ 1 ] | |
刊名 | PROGRESS IN REACTION KINETICS AND MECHANISM |
2018 | |
卷号 | 43期号:2页码:166-172 |
关键词 | dicyclopentadiene monoformyltricyclodecenes hydroformylation ZnO |
ISSN号 | 1468-6783 |
DOI | 10.3184/146867818X15233705894356 |
英文摘要 | Five types of 0.006 wt% Rh catalyst supported on the surfaces of Al2O3, ZnO, TiO2(rutile), TiO2(anatase) and CeO2 were prepared by the incipient wetness method and used to catalyse the conversion of dicyclopentadiene (DCPD) to monoformyltricyclodecenes (MFTD). The 0.006 wt% Rh/ZnO catalyst showed the highest performance of the catalysts investigated and a 95.5% MFTD yield with 100% MFTD selectivity could be achieved. This suggested that there may be a key role for the carrier on the catalytic performance in the DCPD hydroformylation. Furthermore, the kinetic profiles for DCPD hydroformylation over the 0.006 wt% Rh/ZnO catalyst have been examined systematically to explore the effect of reaction temperature on the catalytic performance. These data collectively suggested that a specific reaction temperature might enhance DCPD hydroformylation, possibly owing to agglomeration of the active sites at higher reaction temperatures. |
WOS记录号 | WOS:000436453500007 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7263] |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 |
通讯作者 | Wang, TF (Wang, Tianfu)[ 1 ] |
作者单位 | 1.Xinjiang Qual Prod Supervis & Inspect Inst Techno, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Li, CY ,Li, HY ,Zhang, LB ,et al. Hydroformylation of dicyclopentadiene to monoformyltricyclodecenes over supported ultra-low content Rh catalysts[J]. PROGRESS IN REACTION KINETICS AND MECHANISM,2018,43(2):166-172. |
APA | Li, CY ,Li, HY ,Zhang, LB ,Ma, YB ,&Wang, TF .(2018).Hydroformylation of dicyclopentadiene to monoformyltricyclodecenes over supported ultra-low content Rh catalysts.PROGRESS IN REACTION KINETICS AND MECHANISM,43(2),166-172. |
MLA | Li, CY ,et al."Hydroformylation of dicyclopentadiene to monoformyltricyclodecenes over supported ultra-low content Rh catalysts".PROGRESS IN REACTION KINETICS AND MECHANISM 43.2(2018):166-172. |
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