Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials | |
Han, GP (Han, Guopeng)[ 1,2 ]; Wang, Y (Wang, Ying)[ 1 ]; Zhang, BB (Zhang, Bingbing)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ] | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL |
2018 | |
卷号 | 24期号:67页码:17638-17650 |
关键词 | all solid-state lasers deep-ultraviolet fluorooxoborates nonlinear optical crystal |
ISSN号 | 0947-6539 |
DOI | 10.1002/chem.201802787 |
英文摘要 | Borates are one of the most important classes of functional materials, and several hundreds of artificial borates have been synthesized. The substitution of oxygen by fluorine leads to manifold classes of borates. Fluorooxoborates (also known as fluoroborates), in which the F atoms covalently connect with the B atoms, show additional compositional and structural diversity compared to classic borates. Recently, owing to the large polarizability anisotropy, large HOMO-LUMO gaps, and high hyperpolarizability of the oxyfluoride BOxF4-x building blocks, fluorooxoborates have received unprecedented attention in the search for new ultraviolet (UV) and deep-UV (DUV) nonlinear optical (NLO) materials. Specifically, some compounds have excellent NLO properties that are comparable or superior to KBe2BO3F2, which is the only usable crystal that generates coherent light below 200 nm through a direct second harmonic generation (SHG) process. This Minireview illustrates recent progress on the synthesis, crystal structures, structure-properties relationships and applications of fluorooxoborates. This paper concludes by highlighting the outstanding opportunities offered by NLO fluorooxoborate crystals as an innovative avenue for DUV all solid-state coherent light generation. |
WOS记录号 | WOS:000451888300003 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7325] |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Pan, SL (Pan, Shilie)[ 1 ] |
作者单位 | 1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Han, GP ,Wang, Y ,Zhang, BB ,et al. Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(67):17638-17650. |
APA | Han, GP ,Wang, Y ,Zhang, BB ,&Pan, SL .(2018).Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials.CHEMISTRY-A EUROPEAN JOURNAL,24(67),17638-17650. |
MLA | Han, GP ,et al."Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials".CHEMISTRY-A EUROPEAN JOURNAL 24.67(2018):17638-17650. |
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