Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)(2)(IO3)(4)O, Ba-3[(MoO2)(2)(10(3))(4)O(OH)(4)]center dot 2H(2)O, and Sr[(MoO2)(6)(IO4) O-2(4)]center dot H2O | |
Li, YH (Li, Yahui)[ 1,2 ]; Wu, HP (Wu, Hongping)[ 1 ]; Zhang, BB (Zhang, Bingbing)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Han, GP (Han, Guopeng)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1 ] | |
刊名 | INORGANIC CHEMISTRY |
2019 | |
卷号 | 57期号:15页码:9376-9384 |
ISSN号 | 0020-1669 |
DOI | 10.1021/acs.inorgchem.8b01365 |
英文摘要 | The three metal iodates Ba(MoO2)(2)(IO3)(4)O (1), Ba-3 [(MoO2)(2)(IO3)(4)O(OH)(4)]center dot 2H(2)O (2), and Sr-[(MoO2)(6)(IO4)(2)O-4]center dot H2O (3) have been successfully synthesized by introducing second-order Jahn-Teller distorted Mo6+ cations by a mild hydrothermal method. Single-crystal X-ray diffraction (XRD) was used to determine the structures of the three title compounds. In compound 1, the [Mo2O11 ](10-) dimers connect with the [IO3](-) units by sharing oxygen atoms to form two-dimensional (2D) layers that are separated by the Ba2+ cations. For comparison, the [Mo2O11](10-) dimers and the [IO3](-) units are isolated in compound 2, and they are connected by the [BaO11](20-) polyhedra forming a 3D network. For compound 3, the [MoO6](6-) polyhedra link with each other by corner and edge sharing to build 2D corrugated layers with tunnels containing isolated [IO4](3-) units. The [SrO9](16-) polyhedra link the 2D corrugated layers to form a 3D network. The infrared (IR) spectra, the ultraviolet-visible- near-infrared (UV-vis-NIR) diffuse reflectance spectra, and thermal stabilities of compounds 1 and 2 are presented. In addition, the theoretical calculations are also carried out to evaluate their band gaps and density of states. |
WOS记录号 | WOS:000441477100079 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7250] |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Pan, SL (Pan, Shilie)[ 1 ] |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Li, YH ,Wu, HP ,Zhang, BB ,et al. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)(2)(IO3)(4)O, Ba-3[(MoO2)(2)(10(3))(4)O(OH)(4)]center dot 2H(2)O, and Sr[(MoO2)(6)(IO4) O-2(4)]center dot H2O[J]. INORGANIC CHEMISTRY,2019,57(15):9376-9384. |
APA | Li, YH ,Wu, HP ,Zhang, BB ,Yang, ZH ,Han, GP ,&Pan, SL .(2019).Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)(2)(IO3)(4)O, Ba-3[(MoO2)(2)(10(3))(4)O(OH)(4)]center dot 2H(2)O, and Sr[(MoO2)(6)(IO4) O-2(4)]center dot H2O.INORGANIC CHEMISTRY,57(15),9376-9384. |
MLA | Li, YH ,et al."Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)(2)(IO3)(4)O, Ba-3[(MoO2)(2)(10(3))(4)O(OH)(4)]center dot 2H(2)O, and Sr[(MoO2)(6)(IO4) O-2(4)]center dot H2O".INORGANIC CHEMISTRY 57.15(2019):9376-9384. |
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