Effects of Mo content on the grain size, hardness and anti-wear performance of electrodeposited nanocrystalline and amorphous Ni-Mo alloys | |
Liu, J. H.1,2; Yan, J. X.1,2; Pei, Z. L.2; Gong, J.2; Sun, C.2 | |
刊名 | SURFACE & COATINGS TECHNOLOGY |
2020-12-25 | |
卷号 | 404页码:11 |
关键词 | Electrodeposition Deposition rate Hardness Hall-Petch Wear resistance Archard law |
ISSN号 | 0257-8972 |
DOI | 10.1016/j.surfcoat.2020.126476 |
通讯作者 | Pei, Z. L.(zlpei@imr.ac.cn) ; Sun, C.(csun@imr.ac.cn) |
英文摘要 | Ni-Mo alloys with various Mo contents are prepared by electrodeposition in sulfate-citrate acid solutions under different temperature, pH, stirring rate, current density and MoO42- concentration. Influences of Mo content on the grain size, hardness and wear resistance are studied. Results show that the increase in Mo content decreases the deposition rate of Ni-Mo alloys prepared at a constant temperature. As-prepared alloys are composed of nanocrystalline Ni(Mo) solid solution when Mo is less than 24.4 at.%. The grain size of alloys decreases with the increment of Mo content. Amorphous phase appears in deposits when Mo content exceeds 24.4-27.3 at.%. Hardness and wear resistance of alloys firstly increases with Mo content, and then it has a decline due to the formation of amorphous. Additionally, Hall-Petch (HP) relationship is found in deposits as the grain size decreases from 12.4 nm to 7.9 nm, and then the inverse HP relationship appears with the further decrease in grain size to 1.5 nm. Meanwhile, traditional Archard law is found in Ni-Mo alloys with Mo content in the range of 6.3-27.3 at.%. Additionally, HP breakdown causes a variation of wear resistance at the critical grain size of 7.9 nm. |
资助项目 | National Science and Technology Major Project[2017-VII-0012-0108] |
WOS研究方向 | Materials Science ; Physics |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000597889400040 |
资助机构 | National Science and Technology Major Project |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/158844] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Pei, Z. L.; Sun, C. |
作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, 96 Jinzhai Rd, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Shichangzu Innovat Ctr Adv Mat, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, J. H.,Yan, J. X.,Pei, Z. L.,et al. Effects of Mo content on the grain size, hardness and anti-wear performance of electrodeposited nanocrystalline and amorphous Ni-Mo alloys[J]. SURFACE & COATINGS TECHNOLOGY,2020,404:11. |
APA | Liu, J. H.,Yan, J. X.,Pei, Z. L.,Gong, J.,&Sun, C..(2020).Effects of Mo content on the grain size, hardness and anti-wear performance of electrodeposited nanocrystalline and amorphous Ni-Mo alloys.SURFACE & COATINGS TECHNOLOGY,404,11. |
MLA | Liu, J. H.,et al."Effects of Mo content on the grain size, hardness and anti-wear performance of electrodeposited nanocrystalline and amorphous Ni-Mo alloys".SURFACE & COATINGS TECHNOLOGY 404(2020):11. |
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