Small-Sized and Contacting Pt-WC Nanostructures on Graphene as Highly Efficient Anode Catalysts for Direct Methanol Fuel Cells | |
Wang, Ruihong ; Xie, Ying ; Shi, Keying ; Wang, Jianqiang(王建强) ; Tian, Chungui ; Shen, Peikang ; Fu, Honggang | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL |
2012 | |
卷号 | 18期号:24页码:7443 |
ISSN号 | 0947-6539 |
英文摘要 | The synergistic effect between Pt and WC is beneficial for methanol electro-oxidation, and makes PtWC catalyst a promising anode candidate for the direct methanol fuel cell. This paper reports on the design and synthesis of small-sized and contacting PtWC nanostructures on graphene that bring the synergistic effect into full play. Firstly, DFT calculations show the existence of a strong covalent interaction between WC and graphene, which suggests great potential for anchoring WC on graphene with formation of small-sized, well-dispersed WC particles. The calculations also reveal that, when Pt attaches to the pre-existing WC/graphene hybrid, Pt particles preferentially grow on WC rather than graphene. Our experiments confirmed that highly disperse WC nanoparticles (ca. 5 nm) can indeed be anchored on graphene. Also, Pt particles 23 nm in size are well dispersed on WC/graphene hybrid and preferentially grow on WC grains, forming contacting PtWC nanostructures. These results are consistent with the theoretical findings. X-ray absorption fine structure spectroscopy further confirms the intimate contact between Pt and WC, and demonstrates that the presence of WC can facilitate the crystallinity of Pt particles. This new PtWC/graphene catalyst exhibits a high catalytic efficiency toward methanol oxidation, with a mass activity 1.98 and 4.52 times those of commercial PtRu/C and Pt/C catalysts, respectively. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000304755700017 |
公开日期 | 2013-09-11 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/12913] |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Wang, Ruihong,Xie, Ying,Shi, Keying,et al. Small-Sized and Contacting Pt-WC Nanostructures on Graphene as Highly Efficient Anode Catalysts for Direct Methanol Fuel Cells[J]. CHEMISTRY-A EUROPEAN JOURNAL,2012,18(24):7443. |
APA | Wang, Ruihong.,Xie, Ying.,Shi, Keying.,Wang, Jianqiang.,Tian, Chungui.,...&Fu, Honggang.(2012).Small-Sized and Contacting Pt-WC Nanostructures on Graphene as Highly Efficient Anode Catalysts for Direct Methanol Fuel Cells.CHEMISTRY-A EUROPEAN JOURNAL,18(24),7443. |
MLA | Wang, Ruihong,et al."Small-Sized and Contacting Pt-WC Nanostructures on Graphene as Highly Efficient Anode Catalysts for Direct Methanol Fuel Cells".CHEMISTRY-A EUROPEAN JOURNAL 18.24(2012):7443. |
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