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Atmospheric Corrosion Behaviour of Benzotriazole Treated Cu-based Coins in Synthetic Sweat
Huang, Songpeng1,2; Song, Xuexin1,2; Pan, Chen1,2; Cao, Gongwang1,2; Wang, Zhenyao1,2
刊名INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
2020-08-01
卷号15期号:8页码:7693-7708
关键词Copper coins Wet-Dry cyclic synthetic sweat BTA (Benzotriazole)
ISSN号1452-3981
DOI10.20964/2020.08.33
通讯作者Wang, Zhenyao(zhywang@imr.ac.cn)
英文摘要The atmospheric corrosion behavior of benzotriazole treated Cu-based coins in synthetic sweat was investigated. Electrochemical impedance spectroscopy showed that the protective effect of BTA on copper coins gradually failed in synthetic sweat with the prolongation of immersion time. The copper coin coated with BTA protective film had a faster corrosion rate under cyclic wet-dry test of regularly wetting synthetic sweat. From the composition analysis of protective film and corrosion products, BTA not only complexed with Cu2+ Cu2+, but also reacted with Zn2+/Ni2+. The thickness of the patina layer can reach to 100 mu m after 240h accelerated experiment, and the corrosion products were simple in composition, mainly basic Cu-2(OH)(3)Cl and oxides of Ni and Zn. However, BTA had little protective effect on copper in synthetic sweat, and didn't affect the composition of final corrosion products.
资助项目National Natural Science Foundation of China[51671197] ; Shenyang Mint Co.,Ltd
WOS研究方向Electrochemistry
语种英语
出版者ESG
WOS记录号WOS:000560655800045
资助机构National Natural Science Foundation of China ; Shenyang Mint Co.,Ltd
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/140352]  
专题金属研究所_中国科学院金属研究所
通讯作者Wang, Zhenyao
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Huang, Songpeng,Song, Xuexin,Pan, Chen,et al. Atmospheric Corrosion Behaviour of Benzotriazole Treated Cu-based Coins in Synthetic Sweat[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2020,15(8):7693-7708.
APA Huang, Songpeng,Song, Xuexin,Pan, Chen,Cao, Gongwang,&Wang, Zhenyao.(2020).Atmospheric Corrosion Behaviour of Benzotriazole Treated Cu-based Coins in Synthetic Sweat.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,15(8),7693-7708.
MLA Huang, Songpeng,et al."Atmospheric Corrosion Behaviour of Benzotriazole Treated Cu-based Coins in Synthetic Sweat".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 15.8(2020):7693-7708.
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